Pierre Braunstein
University of Strasbourg
674 Papers
9.4K Citations
Pierre Braunstein is an academic researcher from University of Strasbourg. The author has contributed to research in topics: Ligand & Chemistry. The author has an hindex of 59, co-authored 651 publications. Previous affiliations of Pierre Braunstein include Institut Français & ASTRON.
Chat about Author
Papers
Structurally characterized intermediates in the stepwise insertion of CO-ethylene or CO-methyl acrylate into the metal-carbon bond of Pd(II) complexes stabilized by (phosphinomethyl)oxazoline ligands.
TL;DR: The initial CO-ethylene or CO-methyl acrylate insertion steps into the Pd-Me bond of methylpalladium(II) complexes with (phosphinomethyl)oxazoline ligands, leading to metallacycles, have been fully characterized, including by X-ray diffraction.
Dual Emission of a Cyclic Hexanuclear Gold(I) Complex. Interplay between Au3 and Au2 Ligand-Supported Luminophores
Pengfei Ai,Matteo Mauro,Andreas A. Danopoulos,Andreas A. Danopoulos,Alvaro Muñoz-Castro,Pierre Braunstein +5 more
TL;DR: In this paper, the photoluminescence of complex [Au2Cl(μ-P-C-κP,κC,κN)]3 (1), featuring a ligand-suppor.
•Journal Article
Dual Emission of a Cyclic Hexanuclear Gold(I) Complex. Interplay between Au₃ and Au₂ Ligand-Supported Luminophores
TL;DR: In this paper, the photoluminescence of complex [Au₂Cl(μ-P-C-κP,κC,κN)] is attributed to radiative relaxation of two excited states centered on the central Au₆ skeleton arising from 5dσ* → 6pσ excitation.
Perturbing the spin crossover transition activation energies in Fe(H2B(pz)2)2(bipy) with zwitterionic additions.
Paulo S. Costa,Guanhua Hao,Alpha T. N'Diaye,Lucie Routaboul,Pierre Braunstein,Xin Zhang,Jian Zhang,Bernard Doudin,Axel Enders,Axel Enders,Peter A. Dowben +10 more
TL;DR: It is demonstrated here that the process of exciting the [Fe{H2B(pz)2}2(bipy)] moiety, in the presence of with C6H2([Formula: see text])2, to an electronic state characteristic of the high spin state though incident x-ray fluences, has a thermal activation energies determined to 14-18 meV.
Trifunctional pNHC, Imine, Pyridine Pincer-Type Iridium(III) Complexes: Synthetic, Structural, and Reactivity Studies
TL;DR: Iridium(III) complexes with a trifunctional pincer ligand containing protic N-heterocyclic carbene (pNHC), pyridine, and imine donor groups were obtained in two sequential steps: (i) protonation of 2-(1-(2,6-diisopropylphenylimino)ethyl)-6-(1-imidazolyl)pyridine (LCH; the superscript specifies the position of the tautomerizable H atom in the imidazole ring) with