Photocatalytic, electrocatalytic and photoelectrocatalytic degradation of pharmaceuticals in aqueous media: Analytical methods, mechanisms, simulations, catalysts and reactors

Abstract Conventional methods to clean wastewater actually lead to incomplete treatments, calling for advanced technologies to degrade recalcitrant pollutants. Herein we review solar photo-oxidation to degrade the recalcitrant contaminants in industrial wastewater, with focus on photocatalysts, reactor design and the photo-Fenton process. We discuss limitations due to low visible-light absorption, catalyst collection and reusability, and production of toxic by-products. Photodegradation of refractory organics by solar light is controlled by pH, photocatalyst composition and bandgap, pollutant properties and concentration, irradiation type and intensity, catalyst loading, and the water matrix. 

/pdf/solar-photo-oxidation-of-recalcitrant-industrial-wastewater-19f6nnhg.pdf

Solar photo-oxidation of recalcitrant industrial wastewater: a review

A review toward contaminants of emerging concern in Brazil: Occurrence, impact and their degradation by advanced oxidation process in aquatic matrices.

The vast majority of current technologies used for wastewater treatment are unable to remove pharmaceutical micropollutants. These are discharged to surface water bodies and cause serious problems for fragile natural ecosystems. The expansion of the current legislation for surface water, including the addition of new priority substances, including nine pharmaceuticals, has already been published by the European Commission. After entering into force, every EU member state will have to ensure the monitoring and limitation of the discharging of listed pharmaceuticals. Since current treatment methods are insufficient, new technology needs to be developed. Photochemical advanced oxidation processes (AOPs) are among the most tested methods for wastewater treatment and show high micropollutant removal efficiency. Thus, photochemical AOPs seem to be a promising way to reduce the pharmaceutical burden in wastewater. However, there are still challenges limiting the wide and simple use in wastewater treatment plants. This review was written to fulfill the necessity of summarizing and assessing of current trends in the usage of photochemical AOPs in the treatment of real wastewater matrices, focusing on pharmaceutical micropollutants. To the best of the author's knowledge, the topic was processed for the first time. 

Removal of pharmaceutical micropollutants from real wastewater matrices by means of photochemical advanced oxidation processes – A review

Removal of chloramphenicol antibiotics in natural and engineered water systems: Review of reaction mechanisms and product toxicity.

Solar photo-Fenton treatment of the anti-cancer drug anastrozole in different aqueous matrices at near-neutral pH: Transformation products identification, pathways proposal, and in silico (Q)SAR risk assessment

Antineoplastic agents present potential hazards to human health and the environment. For this reason, these compounds have attracted a great deal of attention from researchers in the environmental sciences field. In order to help guide future research, it is important to understand the current state of investigation of the occurrence of these microcontaminants and methods for their removal, especially focusing on Fenton and photo-Fenton processes applied to various aqueous matrices in which this class of pharmaceuticals is present. For this purpose, a systematic review of these topics was performed by bibliometric analysis of articles published during the last decade and available in the Scopus and Web of Science databases. This study enables visualization of the current panorama and trends in this field, providing a guide for future collaborative research and exchange of knowledge. Various strategies have been suggested to improve the efficiency of Fenton and photo-Fenton processes, mainly by means of the application of multiples additions of iron, the use of heterogeneous catalysts, and/or the use of chelating agents. Some studies have evaluated different radiation sources employed for photo-Fenton processes, such as solar and/or artificial radiation. In turn, the identification of transformation products generated by Fenton and photo-Fenton treatments, together with their evaluation by in silico (Q)SAR predictions or experimental toxicological bioassays, are related subjects that have been less reported in published works and that should be studied in depth. These subjects can support treatment evaluations that are more realistic, considering their limitations or potentials.

Trends in Fenton and photo-Fenton processes for degradation of antineoplastic agents in water matrices: current knowledge and future challenges evaluation using a bibliometric and systematic analysis.

Among the various classes of pharmaceuticals, antineoplastic agents require particular attention. This work investigates the degradation of the anticancer drugs anastrozole (ANZ) and methotrexate (MTX) by the solar photo-Fenton (SPF) process under different experimental conditions and in different aqueous matrices. Tentative identification of the treatment transformation products (TPs) was performed by suspect screening, employing a purpose-built database containing thirty-three TPs from ANZ and MTX. The experimental condition that achieves the most favorable degradation of ANZ and MTX in real hospital wastewater was pH 5 and multiples additions of Fe2+. This condition provided a reduction of ANZ and MTX of 30 % and 70 %, respectively. Eighteen MTX TPs and five ANZ TPs were tentatively identified in the analyzed samples. After tentative identification, quantitative structure-activity relationship ((Q)SAR) in silico methods were used to predict eight endpoints of environmental risk of the selected analytes. When different possible structures could be proposed, all the possibilities were considered, resulting in fifty-nine structures evaluated. TOPSIS multicriteria decision-making method was used to rank the compounds according to their environmental concern, based on (Q)SAR predictions. As main results, TOPSIS ranking showed that all ANZ TPs and most MTX TPs showed higher environmental risk potential than the parent compounds. The findings highlighted the importance of qualitative tentative identification of TPs and their monitoring throughout treatments, as well as risk assessment using various endpoints simultaneously. The proposed approach can provide objective and holistic evaluation of treatment processes. 

Use of multi-criteria ranking method for environmental risk assessment of antineoplastic agents and their transformation products

Handle everyday research tasks with reliable, citation-backed results

Your personal Research Agent to handle research tasks with citation-backed results

Popular Tasks used by Researchers

How can I help with your research?

Meet SciSpace

Get more enhanced response by uploading the PDFs you want me to reference.

No relevant PDFs in your library

SciSpace is the AI research assistant for academics. Run systematic literature reviews on 280M+ papers, and write papers with cited sources. Trusted by 1M+ students, PhDs & researchers.

SciSpace | AI for Research

Analyze PDFs

Code & Manuscripts

Funding & Grants

Literature & Patents

Medical & Clinical Data

Systematic Review

Visualize & Present

Web & Data

Build a Google Scholar-like website for your research.

Build a website

Create charts and images for your research

Create a Chart

Write a paper for submission to a journal

Draft a manuscript

Patent Search

Design eye-catching scientific posters in minutes.

Scientific Poster Generation

Systematic Literature Review

One task is running at the moment. Your messages will be shown right after.

Drag and drop or click here to browse

Loved by <highlight>1 million+</highlight> researchers

Extract a list of specific topics and their sources from unstructured text

Topics

Compare and analyze relevant papers that matches with your search

Papers

Get insights from PDFs and bookmarked papers from your library

My library

Recent searches

Try searching for:

Catch AI-generated content in scholarly and non-scholarly content

{ai} Detector

Ai Writer

Get PDF Summaries, highlighted text explanations 

Chat with PDF

Effortlessly create in-text citations and bibliographies in APA and 2,500 other formats

Citation generator

Get explanations, summaries, and answers on academic papers

Ease up your research workflow with {scispace}'s cohort of exciting AI tools

Elevate your academic writing skills and convey your ideas the way you want

Paraphraser

Explore our range of reading and writing tools

Your file is being prepared and should be ready in a few minutes. If it's a large file, it might take a bit longer. You can close this window, and we'll email you the file when it's done.

You have reached a maximum limit of <strong>{limit}</strong> columns in the table. Remove at least <strong>1</strong> column to add or create another one.

Pedro Sanabria

Author Tools

Chat about Author

Papers

Solar photo-Fenton treatment of the anti-cancer drug anastrozole in different aqueous matrices at near-neutral pH: Transformation products identification, pathways proposal, and in silico (Q)SAR risk assessment

Trends in Fenton and photo-Fenton processes for degradation of antineoplastic agents in water matrices: current knowledge and future challenges evaluation using a bibliometric and systematic analysis.

Use of multi-criteria ranking method for environmental risk assessment of antineoplastic agents and their transformation products