Anodic TiO2 nanotubes have been studied widely for two decades because of their regular tubular structures and extensive applications. However, the formation mechanism of anodic TiO2 nanotubes remains unclear, because it is difficult to find convincing evidence for popular field-assisted dissolution or field-assisted injection theories and the oxygen bubble model. Here, in a bid to find direct evidence that oxygen bubbles form nanotube embryos, a new method is applied to handle this challenge. Before nanotube formation, a dense cover layer was formed to make nanotubes grow more slowly. Many completely enclosed nanotube embryos formed by oxygen bubbles were found beneath the dense cover layer for the first time. The formation of these enclosed and hollow gourd-shaped embryos is convincing enough to prove that the nanotubes are formed by the oxygen bubble mold, similar to inflating a football, rather than by field-assisted dissolution. Based on the ‘oxygen bubble model’ and ionic current and electronic current theories, the formation and growth process of nanotube embryos is explained clearly for the first time. These interesting findings indicate that the ‘oxygen bubble model’ and ionic current and electronic current theories also apply to anodization of other metals.

/pdf/evidence-of-oxygen-bubbles-forming-nanotube-embryos-in-4orfonosh6.pdf

Evidence of oxygen bubbles forming nanotube embryos in porous anodic oxides

Owing to the great development potential of porous anodic oxides (PAO) in many fields, research on their formation mechanisms, fabrication processes and applications has a history of more than ten years. 

/pdf/a-review-research-progress-on-the-formation-mechanism-of-1vdhw0ce.pdf

A review: research progress on the formation mechanism of porous anodic oxides

Understanding the influence of electrolyte aging in electrochemical anodization of titanium.

The applied potential, time, and water content are crucial factors in the electrochemical anodization process because the growth of one-dimensional nanotubes can be accelerated by enhancing the corrosive effect. We investigated the effect of the water content on the resistive switching (RS) properties of Ti foils by anodizing the foils and varying the water content in an electrolyte (1-10 vol %). By increasing the water content, we facilitated a slow transition from nanopores to nanotubes and realized an increase in the tube wall diameter and tube length. All of the fabricated memristive devices exhibited a reliable and reproducible bipolar resistive switching effect. The optimized device exhibited bipolar RS properties with good dc endurance (104 cycles) and data retention capability (105 s). Our results suggest that as the water content increases to 5 vol %, the RS process improves; further increases in the water content impair the RS process.

Unraveling the Effect of the Water Content in the Electrolyte on the Resistive Switching Properties of Self-Assembled One-Dimensional Anodized TiO2 Nanotubes.

By adjusting the oxidation voltage, electrolyte, anodizing time and other parameters, TiO2 nanotubes with high aspect ratio can be prepared by oxidation in organic system because anodic oxidation m...

Recent Progress in Anodic Oxidation of TiO2 Nanotubes and Enhanced Photocatalytic Performance: A Short Review

Debunking the effect of water content on anodizing current: Evidence against the traditional dissolution theory

Growth of porous anodic TiO2 in silver nitrate solution without fluoride: Evidence against the field-assisted dissolution reactions of fluoride ions

Handle everyday research tasks with reliable, citation-backed results

Your personal Research Agent to handle research tasks with citation-backed results

Popular Tasks used by Researchers

How can I help with your research?

Meet SciSpace

Get more enhanced response by uploading the PDFs you want me to reference.

No relevant PDFs in your library

SciSpace is the AI research assistant for academics. Run systematic literature reviews on 280M+ papers, and write papers with cited sources. Trusted by 1M+ students, PhDs & researchers.

SciSpace | AI for Research

Analyze PDFs

Code & Manuscripts

Funding & Grants

Literature & Patents

Medical & Clinical Data

Systematic Review

Visualize & Present

Web & Data

Build a Google Scholar-like website for your research.

Build a website

Create charts and images for your research

Create a Chart

Write a paper for submission to a journal

Draft a manuscript

Patent Search

Design eye-catching scientific posters in minutes.

Scientific Poster Generation

Systematic Literature Review

One task is running at the moment. Your messages will be shown right after.

Drag and drop or click here to browse

Loved by <highlight>1 million+</highlight> researchers

Extract a list of specific topics and their sources from unstructured text

Topics

Compare and analyze relevant papers that matches with your search

Papers

Get insights from PDFs and bookmarked papers from your library

My library

Recent searches

Try searching for:

Catch AI-generated content in scholarly and non-scholarly content

{ai} Detector

Ai Writer

Get PDF Summaries, highlighted text explanations 

Chat with PDF

Effortlessly create in-text citations and bibliographies in APA and 2,500 other formats

Citation generator

Get explanations, summaries, and answers on academic papers

Ease up your research workflow with {scispace}'s cohort of exciting AI tools

Elevate your academic writing skills and convey your ideas the way you want

Paraphraser

Explore our range of reading and writing tools

Your file is being prepared and should be ready in a few minutes. If it's a large file, it might take a bit longer. You can close this window, and we'll email you the file when it's done.

You have reached a maximum limit of <strong>{limit}</strong> columns in the table. Remove at least <strong>1</strong> column to add or create another one.

Nan Lu

Author Tools

Chat about Author

Papers

Debunking the effect of water content on anodizing current: Evidence against the traditional dissolution theory

Growth of porous anodic TiO2 in silver nitrate solution without fluoride: Evidence against the field-assisted dissolution reactions of fluoride ions