N. Alam
École Normale Supérieure
5 Papers
109 Citations
N. Alam is an academic researcher from École Normale Supérieure. The author has contributed to research in topics: Nucleophilic substitution & Radical-nucleophilic aromatic substitution. The author has an hindex of 3, co-authored 5 publications.
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Papers
Electrosynthesis of unsymmetrical biaryls using a SRN1 type reaction
TL;DR: In this article, a new synthetic route to unsymmetrical biaryls was described involving an electrochemically induced chain reaction of the S RN 1 type, which was described as an alternative to the traditional S RN 2 type.
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Theory and experimental illustration of preparative electrochemistry using redox catalysis of electron transfer initiated radical chain reactions. Application to the cross-coupling between aryl halides and phenoxide ions
TL;DR: In this article, a general equation predicting the yield of electron transfer initiated radical chain reaction (S RN 1 and related mechanisms) under preparative electrochemical conditions is given for situations where the electron-transfer activation of the chain is performed by means of a redox mediator.
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Electrosynthesis of Unsymmetrical Biaryls Using a SRN1 Type Reaction.
TL;DR: The chlorobenzonitriles (I) react electrochemically with the phenolate (II), generated in situ from the corresponding phenol and potassium tert-butoxide, to give the biaryl derivatives (III) and the phenol (IV).