Issues and challenges in hydrogen separation technologies

A critical review of the production, activation, and morphological characteristic study on functionalized biochar

Graphene-reinforced metal matrix composites: fabrication, properties, and challenges

The global pursuit of sustainable energy is focused on producing hydrogen through electrocatalysis driven by renewable energy. Recently, High entropy alloys (HEAs) have taken the spotlight in electrolysis due to their intriguing cocktail effect, broad design space, customizable electronic structure, and entropy stabilization effect. The tunability and complexity of HEAs allow a diverse range of active sites, optimizing adsorption strength and activity for electrochemical water splitting. This review comprehensively covers contemporary advancements in synthesis technique, design framework, and physio-chemical evaluation approaches for HEA-based electrocatalysts. Additionally, it explores design principles and strategies aimed at optimizing the catalytic activity, stability, and effectiveness of HEAs in hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and overall water splitting. Through an in-depth investigation of these aspects, the complexity inherent in constituent element interactions, reaction processes, and active sites associated with HEAs is aimed to unravel. Eventually, an outlook regarding challenges and impending difficulties and an outline of the future direction of HEA in electrocatalysis is provided. The thorough knowledge offered in this review will assist in formulating and designing catalysts based on HEAs for the next generation of electrochemistry-related applications.

Unlocking the Potential of High Entropy Alloys in Electrochemical Water Splitting: A Review.

Hydrogen-free catalytic depolymerization of waste polyolefins at mild temperatures

Gasification and pyrolysis are thermal processes for converting carbonaceous substances into tar, ash, coke, char, and gas. Pyrolysis produces products such as char, tar, and gas, while gasification transforms carbon-containing products (e.g., the products from pyrolysis) into a primarily gaseous product. The composition of the products and their relative quantities are highly dependent on the configuration of the overall process and on the input fuel. Although in gasification, pyrolysis processes also occur in many cases (yet prior to the gasification processes), gasification is a common description for the overall technology. Pyrolysis, on the other hand, can be used without going through the gasification process. The current study evaluates the most common waste plastics valorization routes for producing gaseous and liquid products, as well as the key process specifications that affected the end final products. The reactor type, temperatures, residence time, pressure, the fluidizing gas type, the flow rate, and catalysts were all investigated in this study. Pyrolysis and waste gasification, on the other hand, are expected to become more common in the future. One explanation for this is that public opinion on the incineration of waste in some countries is a main impediment to the development of new incineration capacity. However, an exceptional capability of gasification and pyrolysis over incineration to conserve waste chemical energy is also essential.

https://www.frontiersin.org/articles/10.3389/fchem.2022.960894/pdf

A review on gasification and pyrolysis of waste plastics

The corrosion of metals, i.e., the initiation and acceleration of the surface deterioration of metals through an electrochemical reaction with the surrounding intrusive environment, is a global concern because of the economic and environmental impacts. Corrosion inhibitors are considered the most practical choice among the available corrosion protection techniques due to their effectiveness in terms of functionality and cost. The use of traditional and toxic corrosion inhibitors has led to environmental issues, arousing the need for green counterparts that are environmentally friendly, easily accessible, biodegradable, and cost-effective. In this review, the utilization of green corrosion inhibitors purely acquired from renewable sources is explored, with an in-depth focus on the recent advancements in the use of fruit and vegetable extracts as green corrosion inhibitors. In particular, fruits and vegetables are natural sources of various phytochemicals that exhibit key potential in corrosion inhibition. To shed light on the true potential of such extracts in the protection of steel in acidic environments, the experimental techniques involved in corrosion inhibition and the mechanism of corrosion inhibition are discussed in detail. The study highlights the potential of fruit and vegetable extracts as non-toxic, economical, and effective corrosion inhibitors in the pursuit of green chemistry. In addition to discussing and outlining the current status and opportunities for employing fruit and vegetable extracts as corrosion inhibitors, the current review outlines the challenges involved in the utilization of such extracts in corrosion inhibition.

/pdf/a-brief-review-on-fruit-and-vegetable-extracts-as-corrosion-314k7tax.pdf

A Brief Review on Fruit and Vegetable Extracts as Corrosion Inhibitors in Acidic Environments

Rapid industrialization is consuming too much energy, and non-renewable energy resources are currently supplying the world’s majority of energy requirements. As a result, the global energy mix is being pushed towards renewable and sustainable energy sources by the world’s future energy plan and climate change. Thus, hydrogen has been suggested as a potential energy source for sustainable development. Currently, the production of hydrogen from fossil fuels is dominant in the world and its utilization is increasing daily. As discussed in the paper, a large amount of hydrogen is used in rocket engines, oil refining, ammonia production, and many other processes. This paper also analyzes the environmental impacts of hydrogen utilization in various applications such as iron and steel production, rocket engines, ammonia production, and hydrogenation. It is predicted that all of our fossil fuels will run out soon if we continue to consume them at our current pace of consumption. Hydrogen is only ecologically friendly when it is produced from renewable energy. Therefore, a transition towards hydrogen production from renewable energy resources such as solar, geothermal, and wind is necessary. However, many things need to be achieved before we can transition from a fossil-fuel-driven economy to one based on renewable energy.

/pdf/environmental-assessment-of-hydrogen-utilization-in-various-1enf83bi.pdf

Environmental Assessment of Hydrogen Utilization in Various Applications and Alternative Renewable Sources for Hydrogen Production: A Review

Maximizing resource efficiency: opportunities for energy recovery from municipal solid waste in Europe

In this article, the effect of absorption time on the surface chemistry and pore structure of activated carbon (AC) from waste leaves of Quercus alba with the H3PO4 chemical activation method. XRD, SEM, EDX, BET, TGA, and FT-IR analyses of prepared AC were used to figure out the properties of the activated carbon. The results demonstrated that the 48 h absorption time of H3PO4 contributed to the highest surface area, 943.2 m2/g, among all the prepared activated carbon samples. As the absorption time of the phosphoric acid activating agent was increased, the surface area initially increased and then started to decrease. The further surface chemical characterization of activated carbon was determined by FT-IR spectroscopic method. Life cycle assessment methodology was employed in order to investigate the environmental impacts associated with the laboratory steps for activated carbon (AC) production. The LCA approach was implemented using OpenLCA 1.10.3 software, while ReCiPe Midpoint (H) was used for environmental impact assessment. The results of the LCA study showed that the impact categories related to toxicity were particularly affected by the utilization of electrical energy (≈90%). The power utilized during laboratory procedures was the main cause of environmental impacts, contributing an average of nearly 70% across all impact categories, with the maximum contribution to the impact category of freshwater ecotoxicity potential (≈97%) and the minimum contribution to land use potential (≈10%).

/pdf/effect-of-absorption-time-for-the-preparation-of-activated-13nh2cfd.pdf

Effect of Absorption Time for the Preparation of Activated Carbon from Wasted Tree Leaves of Quercus alba and Investigating Life Cycle Assessment

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