Controlling dropwise condensation is fundamental to water-harvesting systems, desalination, thermal power generation, air conditioning, distillation towers, and numerous other applications. For any of these, it is essential to design surfaces that enable droplets to grow rapidly and to be shed as quickly as possible. However, approaches based on microscale, nanoscale or molecular-scale textures suffer from intrinsic trade-offs that make it difficult to optimize both growth and transport at once. Here we present a conceptually different design approach—based on principles derived from Namib desert beetles, cacti, and pitcher plants—that synergistically combines these aspects of condensation and substantially outperforms other synthetic surfaces. Inspired by an unconventional interpretation of the role of the beetle’s bumpy surface geometry in promoting condensation, and using theoretical modelling, we show how to maximize vapour diffusion fluxat the apex of convex millimetric bumps by optimizing the radius of curvature and cross-sectional shape. Integrating this apex geometry with a widening slope, analogous to cactus spines, directly couples facilitated droplet growth with fast directional transport, by creating a free-energy profile that drives the droplet down the slope before its growth rate can decrease. This coupling is further enhanced by a slippery, pitcher-plant-inspired nanocoating that facilitates feedback between coalescence-driven growth and capillary-driven motion on the way down. Bumps that are rationally designed to integrate these mechanisms are able to grow and transport large droplets even against gravity and overcome the effect of an unfavourable temperature gradient. We further observe an unprecedented sixfold-higher exponent of growth rate, faster onset, higher steady-state turnover rate, and a greater volume of water collected compared to other surfaces. We envision that this fundamental understanding and rational design strategy can be applied to a wide range of water-harvesting and phase-change heat-transfer applications.

/pdf/condensation-on-slippery-asymmetric-bumps-4426ixsajt.pdf

Condensation on Slippery Asymmetric Bumps

It was recently discovered that condensation growing on a nanostructured superhydrophobic surface can spontaneously jump off the surface, triggered by naturally occurring coalescence events. Many reports have observed that droplets must grow to a size of order 10 μm before jumping is enabled upon coalescence; however, it remains unknown how the critical jumping size relates to the topography of the underlying nanostructure. Here, we characterize the dynamic behavior of condensation growing on six different superhydrophobic nanostructures, where the topography of the nanopillars was systematically varied. The critical jumping diameter was observed to be highly dependent upon the height, diameter, and pitch of the nanopillars: tall and slender nanopillars promoted 2 μm jumping droplets, whereas short and stout nanopillars increased the critical size to over 20 μm. The topology of each surface is successfully correlated to the critical jumping diameter by constructing an energetic model that predicts how large a nucleating embryo needs to grow before it can inflate into the air with an apparent contact angle large enough for jumping. By extending our model to consider any possible surface, it is revealed that properly designed nanostructures should enable nanometric jumping droplets, which would further enhance jumping-droplet condensers for heat transfer, antifogging, and antifrosting applications.

/pdf/tuning-superhydrophobic-nanostructures-to-enhance-jumping-4nl0k5eqee.pdf

Tuning Superhydrophobic Nanostructures to Enhance Jumping-Droplet Condensation

Freshwater scarcity is a global challenge posing threats to the lives and daily activities of humankind such that two-thirds of the global population currently experience water shortages. Atmospheric water, irrespective of geographical location, is considered as an alternative water source. Sorption-based atmospheric water harvesting (SAWH) has recently emerged as an efficient strategy for decentralized water production. SAWH thus opens up a self-sustaining source of freshwater that can potentially support the global population for various applications. In this review, the state-of-the-art of SAWH, considering its operation principle, thermodynamic analysis, energy assessment, materials, components, different designs, productivity improvement, scale-up, and application for drinking water are first extensively explored. Thereafter, the practical integration and potential application of SAWH, beyond drinking water, for wide range of utilities in agriculture, fuel/electricity production, thermal management in building services, electronic devices, and textile are comprehensively discussed. The various strategies to reduce human reliance on natural water resources by integrating SAWH into existing technologies, particularly in underdeveloped countries, in order to satisfy the interconnected needs for food, energy, and water are also examined. This study further highlights the urgent need and future research directions to intensify the design and development of hybrid-SAWH systems for sustainability and diverse applications. This article is protected by copyright. All rights reserved.

Sorption-based Atmospheric Water Harvesting: Materials, Components, Systems, and Applications.

Interfacial-heating solar desalination of high-salinity brine: Recent progress on salt management and water production

The effect of surface-free energy and microstructure on the condensation mechanism of water vapor

Tuning substrate geometry for enhancing water condensation

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Tuning substrate geometry for enhancing water condensation