Michael Karnop
Braunschweig University of Technology
4 Papers
43 Citations
Michael Karnop is an academic researcher from Braunschweig University of Technology. The author has contributed to research in topics: Isopropyl & Adduct. The author has an hindex of 3, co-authored 4 publications.
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Papers
Novel trichlorosilylation and trichlorogermylation of a P-chlorophosphaalkene leading to functionally substituted diphosphenes
TL;DR: The reactions of P-chlorobis(trimethylsilyl)methylenephosphane with hexachlorodisilane or with dichlorogermylene-dioxane afford the new Si-functionalised ditrisyldiphosphene derivative [(Me 3 Si) 2 (Cl 3 Si)-CP] 2 and the related trichloroglomermyl diphosphenes.
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Dichlorogermylene-Alkyldichlorophosphane Reactions Revisited: Characterisation of Bis(trichlorogermyl)phosphanes, Trichlorogermyldiphosphanes, and Ge-P Heterocycles
TL;DR: In this paper, the reactions of alkyldichlorophosphanes 1 (RPCl2; R = tert-butyl: 1a, R = isopropyl; 1b, 1-adamantyl:1c) with the germanium dichloride dioxane complex were followed by 31P NMR.
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Reversible Rearrangements of Chlorophosphane‐Dichlorogermylene Ylides to Trichlorogermylphosphanes — Structure Determination of a Tetranuclear Bis(chlorophosphane)bis(trichlorogermylphosphane) Silver Bromide Complex
Wolf-Walther du Mont,Michael Karnop,Jens Mahnke,Reiner Martens,Christian Druckenbrodt,Jörg Jeske,Peter G. Jones +6 more
TL;DR: In this article, a 1:1 mixture of 4a with 1a is formed by the novel cleavage (chlorogermylation) of the P-P bond of tetraisopropyldiphosphane with germanium tetrachloride.
10
The Suprising Variety of Products from Reactions of P-P Bonds with Dichlorogermylene
TL;DR: In this paper, the insertion of dichlorogermylene (from GcCl2-dioxane) into the P-P bonds of tetraalkyldiphosphanes ((PRR)2) leads 10 dichlorobis(dialkylphosphanyl)germanes 3a-c.