Michael Buback
University of Göttingen
12 Papers
49 Citations
Michael Buback is an academic researcher from University of Göttingen. The author has contributed to research in topics: Polymerization & Radical polymerization. The author has an hindex of 8, co-authored 12 publications. Previous affiliations of Michael Buback include Queen's University.
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Papers
Determination of Intramolecular Chain Transfer and Midchain Radical Propagation Rate Coefficients for Butyl Acrylate by Pulsed Laser Polymerization
TL;DR: In this paper, a method to extract individual free-radical polymerization rate coefficients for butyl acrylate intramolecular chain transfer (backbiting), kbb, and for monomer addition to the resulting midchain radical,, is presented.
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Propagation Rate Coefficients of Acrylate−Methacrylate Free-Radical Bulk Copolymerizations
TL;DR: In this paper, the authors measured the propagation rate coefficients for the binary acrylate−methacrylate copolymerization, and determined the reactivity ratio for each of the four systems.
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Kinetics and Modeling of Free-Radical Batch Polymerization of Nonionized Methacrylic Acid in Aqueous Solution
TL;DR: In this paper, the authors investigated the batch free-radical polymerization of nonionized methacrylic acid (MAA) in aqueous solution at 50 °C and initial monomer concentrations up to 30 wt % MAA.
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Single-pulse pulsed laser polymerization–electron paramagnetic resonance investigations into the termination kinetics of n-butyl acrylate macromonomers
TL;DR: The termination of model mid-chain radicals (MCRs), which mimic radicals that occur in acrylate polymerization over a broad range of reaction conditions, has been studied by single-pulse pulsed laser polymerization (SP-PLP) in conjunction with electron paramagnetic resonance spectroscopy as discussed by the authors.
Modeling termination kinetics of non-stationary free-radical polymerizations
TL;DR: In this article, an equation for the time dependence of free-radical concentration is derived for laser-induced photo-initiator decomposition and an analytical expression for k 1 is derived under the limiting case of T + c -1 (k p M) -1, where c is a dimensionless chain-transfer constant, k p the propagation rate coefficient and M the monomer concentration.
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