In the title compound, [Rh2(C8H8NO)4(C8H7N)], the four acetamidate ligands bridging the dirhodium core are arranged in a 2,2-trans manner. One RhII atom is five-coordinate, in a distorted pyramidal geometry, while the other is six-coord­in­ate, with a disorted octa­hedral geometry. For the six-coord­inate RhII atom, the axial nitrile ligand shows a non-linear Rh–nitrile coordination with an Rh—N—C bond angle of 166.4 (4)° and a nitrile N—C bond length of 1.138 (6) A. Each unique RhII atom is coordinated by a trans pair of N atoms and a trans pair of O atoms from the four acetamide ligands. The Neq—Rh—Rh—Oeq torsion angles on the acetamide bridge varies between 12.55 (11) and 14.04 (8)°. In the crystal, the 3-methyl­benzo­nitrile ring shows a π–π inter­action with an inversion-related equivalent [inter­planar spacing = 3.360 (6) A]. A phenyl ring on one of the acetamide ligands also has a face-to-face π–π inter­action with an inversion-related equivalent [inter­planar spacing = 3.416 (5) A].

(3-Methyl­benzo­nitrile-κN)tetra­kis(μ-N-phenyl­acetamidato)-κ4N:O;κ4O:N-di­rhodium(II)(Rh—Rh)

The complex molecule of the title compound, [Rh2{N(C6H5)COCH3}4(NCC7H7)], has crystallographically-imposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique RhII atom cis to one another. The Neq—Rh—Rh—Oeq torsion angles on the acetamide bridge are 0.75 (7) and 1.99 (9)°. The axial nitrile ligand completes the distorted octa­hedral coordination sphere of one RhII atom and shows a nonlinear coordination, with an Rh—N—C bond angle of 162.8 (5)°; the N—C bond length is 1.154 (7) A.

/pdf/3-methyl-benzo-nitrile-1kn-cis-tetra-kis-m-n-phenyl-4gjar1eovx.pdf

(3-Methyl­benzo­nitrile-1κN)-cis-tetra­kis(μ-N-phenyl­acetamidato)-1:2κ4N:O;1:2κ4O:N-dirhodium(II)(Rh—Rh)

The complex molecule of the title compound, [Rh2{N(C6H5)COCH3}4(C8H7N)2], exhibits inversion symmetry. The four acetamidate ligands bridging the dirhodium core are arranged in a 2,2-trans manner with two N atoms and two O atoms coordinating to each RhII atom trans to one another. The Neq—Rh—Rh—Oeq torsion angles on the acetamidate bridge vary between −4.07 (5) and −6.78 (7)°. The axial nitrile ligands complete the distorted octa­hedral coordination sphere of each RhII atom and show a nonlinear coordination with Rh—N—C bond angles of 151.6 (3) and 152.5 (3)°. The bond lengths of the two nitrile triple bonds are 1.133 (5) and 1.137 (5) A.

/pdf/crystal-structure-of-tetra-kis-m-n-phenyl-acetamidato-k4n-o-45mz9u9t1l.pdf

Crystal structure of tetra­kis­(μ-N-phenyl­acetamidato)-κ4N:O;κ4O:N-bis­[(2-methyl­benzo­nitrile-κN)rhodium(II)](Rh—Rh)

Metal–Metal Bonded Compounds of the Group IX Elements

The complex molecule of the title compound, [Rh2{N(C6H5)COCH3}4(C6H5CN)2], exhibits crystallographically imposed centrosymmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner, with two N atoms and two O atoms coordinating to the unique RhII atom cis to one another. The Neq—Rh—Rh—Oeq torsion angles on the acetamide bridges vary between 1.62 (4) and 1.78 (4)°. The Rh—Rh bond length is 2.4319 (3) A. The axial nitrile ligand completes the distorted octahedral coordination sphere and shows a non-linear coordination with an Rh—N—C bond angle of 167.14 (15)°, while the N—C bond length is 1.135 (3) A.

https://journals.iucr.org/e/issues/2013/06/00/mw2103/mw2103.pdf

cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ4N:O;κ4O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh)

/pdf/characterization-of-complexes-of-2-2-cis-rh2-n-c6h5-coch3-4-ze8zh6b1os.pdf

Characterization of Complexes of 2,2-cis (Rh2(N{C6H5}COCH3)4) with Nitriles.

Handle everyday research tasks with reliable, citation-backed results

Your personal Research Agent to handle research tasks with citation-backed results

Popular Tasks used by Researchers

How can I help with your research?

Meet SciSpace

Get more enhanced response by uploading the PDFs you want me to reference.

No relevant PDFs in your library

SciSpace is the AI research assistant for academics. Run systematic literature reviews on 280M+ papers, and write papers with cited sources. Trusted by 1M+ students, PhDs & researchers.

SciSpace | AI for Research

Analyze PDFs

Code & Manuscripts

Funding & Grants

Literature & Patents

Medical & Clinical Data

Systematic Review

Visualize & Present

Web & Data

Build a Google Scholar-like website for your research.

Build a website

Create charts and images for your research

Create a Chart

Write a paper for submission to a journal

Draft a manuscript

Patent Search

Design eye-catching scientific posters in minutes.

Scientific Poster Generation

Systematic Literature Review

One task is running at the moment. Your messages will be shown right after.

Drag and drop or click here to browse

Loved by <highlight>1 million+</highlight> researchers

Extract a list of specific topics and their sources from unstructured text

Topics

Compare and analyze relevant papers that matches with your search

Papers

Get insights from PDFs and bookmarked papers from your library

My library

Recent searches

Try searching for:

Catch AI-generated content in scholarly and non-scholarly content

{ai} Detector

Ai Writer

Get PDF Summaries, highlighted text explanations 

Chat with PDF

Effortlessly create in-text citations and bibliographies in APA and 2,500 other formats

Citation generator

Get explanations, summaries, and answers on academic papers

Ease up your research workflow with {scispace}'s cohort of exciting AI tools

Elevate your academic writing skills and convey your ideas the way you want

Paraphraser

Explore our range of reading and writing tools

Your file is being prepared and should be ready in a few minutes. If it's a large file, it might take a bit longer. You can close this window, and we'll email you the file when it's done.

You have reached a maximum limit of <strong>{limit}</strong> columns in the table. Remove at least <strong>1</strong> column to add or create another one.

Megan E. Ketron

Author Tools

Chat about Author

Papers

cis-Tetrakis(μ-N-phenylacetamidato)-κ4N:O;κ4O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh)

Characterization of Complexes of 2,2-cis (Rh2(N{C6H5}COCH3)4) with Nitriles.

Megan E. Ketron

Author Tools

Chat about Author

Papers

cis-Tetra­kis(μ-N-phenyl­acetamidato)-κ4N:O;κ4O:N-bis­[(benzo­nitrile-κN)rhodium(II)](Rh—Rh)

Characterization of Complexes of 2,2-cis (Rh2(N{C6H5}COCH3)4) with Nitriles.

cis-Tetrakis(μ-N-phenylacetamidato)-κ4N:O;κ4O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh)