Matthew R. Crawley
State University of New York System
30 Papers
50 Citations
Matthew R. Crawley is an academic researcher from State University of New York System. The author has contributed to research in topics: Chemistry & Medicine. The author has an hindex of 9, co-authored 15 publications.
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Papers
Highly Emissive Self-Assembled BODIPY-Platinum Supramolecular Triangles
Jiong Zhou,Jiong Zhou,Yuzhen Zhang,Guocan Yu,Guocan Yu,Matthew R. Crawley,Cressa Ria P. Fulong,Alan E. Friedman,Sanghamitra Sengupta,Jifu Sun,Qing Li,Feihe Huang,Timothy R. Cook +12 more
TL;DR: A multicomponent approach to self-assembled metallacages that enables design of effective theranostic agents wherein the platinum acceptors are toxic chemotherapeutics and the BODIPY donors are imaging probes and photosensitizers is exploited.
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Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self-Assembly
TL;DR: A suite of coordination-driven self-assembled prisms differing in the molecular clips linking two porphyrin faces in a cofacial arrangement for heterogeneous electrocatalytic oxygen reduction (ORR) highlights how self-assembly can be used to address multi-electron multi-proton transformations using polynuclear catalysts.
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Tuning the Reactivity of Cofacial Porphyrin Prisms for Oxygen Reduction Using Modular Building Blocks.
Matthew R. Crawley,Daoyang Zhang,Amanda N. Oldacre,Christine M. Beavers,Alan E. Friedman,Timothy R. Cook +5 more
TL;DR: In this paper, eight cofacial porphyrin prisms were assembled using coordination-driven self-assembly, which allowed for the rapid synthesis of these architectures in isolated yields as high as 98% for the assembly step.
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Exploring Inner-Sphere Water Interactions of Fe(II) and Co(II) Complexes of 12-Membered Macrocycles To Develop CEST MRI Probes.
Christopher J. Bond,Gregory E. Sokolow,Matthew R. Crawley,Patrick J. Burns,Jordan M. Cox,Ramasamy Mayilmurugan,Janet R. Morrow +6 more
TL;DR: Several paramagnetic Co(II and Fe(II) macrocyclic complexes were prepared with the goal of introducing a bound water ligand to produce paramagnetically shifted water 1H resonances.
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An FeIII Azamacrocyclic Complex as a pH-Tunable Catholyte and Anolyte for Redox-Flow Battery Applications
Pavel B. Tsitovich,Anjula M. Kosswattaarachchi,Matthew R. Crawley,Timothy Y. Tittiris,Timothy R. Cook,Janet R. Morrow +5 more
TL;DR: Given its tunable redox, fast electrochemical kinetics, exceptional stability/cyclability, this complex is promising for the design of aqueous RFB catholytes and anolytes that utilize the earth-abundant element iron.
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