A novel, water-stable, perylene diimide (PDI) based metal-organic framework (MOF), namely, U-1, has been synthesized for selective and sensitive detection of perfluorooctanoic acid (PFOA) in mixed aqueous solutions. The MOF shows highly selective fluorescence turn-on detection via the formation of a PFOA-MOF complex. This PFOA-MOF complex formation was confirmed by various spectroscopic techniques. The detection limit of the MOF for PFOA was found to be 1.68 μM in an aqueous suspension. Upon coating onto cellulose paper, the MOF demonstrated a significantly lower detection limit, down to 3.1 nM, which is mainly due to the concentrative effect of solid phase extraction (SPE). This detection limit is lower than the fluorescence sensors based on MOFs previously reported for PFAS detection. The MOF sensor is regenerable and capable of detecting PFOA in drinking and tap water samples. The PDI-MOF-based sensor reported herein represents a novel approach, relying on fluorescence turn-on response, that has not yet been thoroughly investigated for detecting per- and polyfluoroalkyl substances (PFAS) until now.

Fluorescence Turn-on Detection of Perfluorooctanoic Acid (PFOA) by Perylene Diimide-Based Metal-Organic Framework.

This feature article summarizes the synthesis and application of metal–organic framework-based fluorescence sensors. 

The design, synthesis and application of metal organic frameworks-based fluorescence sensors

Conventional passive packaging plays a crucial role in food manufacturing by protecting foods from various external influences. Most packaging materials are polymer-based plastics derived from fossil carbon sources, which are favored for their versatility, aesthetic appeal, and cost-effectiveness. However, the extensive use of these materials poses significant environmental challenges due to their fossil-based origins and persistence in the environment. Global plastic consumption for packaging is expected to nearly triple by 2060, exacerbating the ecological crisis. Moreover, globalization has increased access to a diverse range of foods from around the world, heightening the importance of packaging in providing healthier and safer foods with extended shelf life. In response to these challenges, there is a growing shift to eco-friendly active packaging that not only protects but also preserves the authentic qualities of food, surpassing the roles of conventional passive packaging. This article provides a comprehensive review on the viability, benefits, and challenges of implementing bio-based biodegradable polymers in active food packaging, with the dual goals of environmental sustainability and extending food shelf life. 

Review of Bio-Based Biodegradable Polymers: Smart Solutions for Sustainable Food Packaging

Polyvinyl chloride-reduced graphene oxide based chemiresistive sensor for sensitive detection of ammonia

The present review article discusses the elementary concepts of the sensor mechanism and various types of materials used for sensor applications. The electrospinning method is the most comfortable method to prepare the device-like structure by means of forming from the fiber structure. Though there are various materials available for sensors, the important factor is to incorporate the functional group on the surface of the materials. The post-modification sanction enhances the efficiency of the sensor materials. This article also describes the various types of materials applied to chemical and biosensor applications. The chemical sensor parts include acetone, ethanol, ammonia, and CO2, H2O2, and NO2 molecules; meanwhile, the biosensor takes on glucose, uric acid, and cholesterol molecules. The above materials have to be sensed for a healthier lifestyle for humans and other living organisms. The prescribed review articles give a detailed report on the Electrospun materials for sensor applications. 

A Review on Electrospun Nanofiber Composites for an Efficient Electrochemical Sensor Applications

Hydrogen peroxide (H2O2) is commonly used as an oxidizing, bleaching, or antiseptic agent. It is also hazardous at increased concentrations. It is therefore crucial to monitor the presence and concentration of H2O2, particularly in the vapor phase. However, it remains a challenge for many state-of-the-art chemical sensors (e.g., metal oxides) to detect hydrogen peroxide vapor (HPV) because of the interference of moisture in the form of humidity. Moisture, in the form of humidity, is guaranteed to be present in HPV to some extent. To meet this challenge, herein, we report a novel composite material based on poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) doped with ammonium titanyl oxalate (ATO). This material can be fabricated as a thin film on electrode substrates for use in chemiresistive sensing of HPV. The adsorbed H2O2 will react with ATO, causing a colorimetric response in the material body. Combining colorimetric and chemiresistive responses resulted in a more reliable dual-function sensing method that improved the selectivity and sensitivity. Moreover, the composite film of PEDOT:PSS-ATO could be coated with a layer of pure PEDOT via in situ electrochemical synthesis. The pure PEDOT layer was hydrophobic, shielding the sensor material underneath from coming into contact with moisture. This was shown to mitigate the interference of humidity when detecting H2O2. A combination of these material properties makes the double-layer composite film, namely PEDOT:PSS-ATO/PEDOT, an ideal sensor platform for the detection of HPV. For example, upon a 9 min exposure to HPV at a concentration of 1.9 ppm, the electrical resistance of the film increased threefold, surpassing the bounds of the safety threshold. Meanwhile, the colorimetric response observed was 2.55 (defined as the color change ratio), a ratio at which the color change could be easily seen by the naked eye and quantified. We expect that this reported dual-mode sensor will find extensive practical applications in the fields of health and security with real-time, onsite monitoring of HPV.

/pdf/pedot-films-doped-with-titanyl-oxalate-as-chemiresistive-and-2f9z6mpt.pdf

PEDOT Films Doped with Titanyl Oxalate as Chemiresistive and Colorimetric Dual-Mode Sensors for the Detection of Hydrogen Peroxide Vapor

Hydrogen peroxide (aqueous solution of H2O2) is one of the most used reagents i n medical sterilization, environmental disinfection, food storage, and other fields. However, hydrogen peroxide has the potential to cause serious harm to biological health and environmental safety. There are many methods (especially electrochemistry) for H2O2 detection in liquid phase systems, but a lack of methods for vapor detection. This is due to its colorless and tasteless nature, as well as the oxidative activity of the molecule and its coexistence with humidity. In this study, poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS), one of the most commercially successful and widely used conductive polymers, was employed to fabricate an all-organic chemiresistive sensor for simple, real-time, and on-site sensing of hydrogen peroxide vapor (HPV) at room temperature. In comparison with pristine PEDOT:PSS film, the PEDOT:PSS/PEDOT film was prepared by in situ electrochemical polymerization. Upon exposure to different concentrations of HPV, it was found that the hydrophobic and porous PEDOT layer could weaken the interference of humidity in HPV sensing, resulting in a more sensitive and accurate response. At 1.0 ppm HPV concentration, the resistance signal response was increased by nearly 89% compared with the pristine PEDOT:PSS film. This PEDOT-film-based chemiresistive sensor showcases the possibility for further development of nonenzymatic HPV monitoring technology.

/pdf/pedot-pss-pedot-film-chemiresistive-sensors-for-hydrogen-3mkwgwit.pdf

PEDOT:PSS/PEDOT Film Chemiresistive Sensors for Hydrogen Peroxide Vapor Detection under Ambient Conditions

Psychrotrophic bacteria, commonly called spoilage bacteria, can produce highly toxic hydrogen sulfide (H2S) in meat products. Thus, monitoring the presence of hydrogen sulfide in meat samples is crucial for food safety and storage. Here, we report a unique chemical sensor based on supramolecular nanorods synthesized via copper ion induced self-assembly of N,N-bis[aspartic potassium salt]-3,4,9,10-perylenetetracarboxylic diimide (APBI-K). The self-assembled nanorods can specifically detect sulfide with a detection limit of 0.181 μM in solution. The nanorods suspended in pure water show a turn-on fluorescence sensing behavior along with color change, acting as a dual fluorometric and colorimetric sensor. Spectroscopic investigation confirms the sensing mechanism due to copper ion displacement induced by the association with sulfide. Based on the high selectivity and sensitivity, supramolecular nanorod sensors were successfully employed to detect H2S in spoiled meat sample as well as dissolved H2S in water.

/pdf/a-dual-fluorometric-and-colorimetric-sulfide-sensor-based-on-md7pwgxt.pdf

A Dual Fluorometric and Colorimetric Sulfide Sensor Based on Coordinating Self-Assembled Nanorods: Applicable for Monitoring Meat Spoilage

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Papers

Fluorescence Turn-on Detection of Perfluorooctanoic Acid (PFOA) by Perylene Diimide-Based Metal-Organic Framework.

PEDOT Films Doped with Titanyl Oxalate as Chemiresistive and Colorimetric Dual-Mode Sensors for the Detection of Hydrogen Peroxide Vapor

PEDOT:PSS/PEDOT Film Chemiresistive Sensors for Hydrogen Peroxide Vapor Detection under Ambient Conditions

A Dual Fluorometric and Colorimetric Sulfide Sensor Based on Coordinating Self-Assembled Nanorods: Applicable for Monitoring Meat Spoilage