Matthew Gray
Queen's University
5 Papers
78 Citations
Matthew Gray is an academic researcher from Queen's University. The author has contributed to research in topics: Metalation & Friedel–Crafts reaction. The author has an hindex of 3, co-authored 5 publications. Previous affiliations of Matthew Gray include University of Guelph.
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Papers
Carbanionic Friedel-Crafts equivalents. regioselective directed ortho and remote metalation-C-N cross coupling routes to acridones and dibenzo[b,f]azepinones.
TL;DR: Carbanion-mediated general regioselective routes to acridones 4 and dibenzo[b,f]azepinones 20 are described and low energy conformations for compounds 18b and 23 indicate that the cyclization reactions are under kinetic control.
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Directed ortho and Remote Metalation - Cross Coupling Connections. Buchwald-Hartwig Synthesis of 2-Carbamoyl Diarylamines. Regioselective Anionic Routes to Acridones, Oxindoles, Dibenzo-[b,f]azepinones, and Anthranilate Esters
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Directed ortho and Remote Metalation—Cross Coupling Connections. Buchwald—Hartwig Synthesis of 2-Carbamoyl Diarylamines. Regioselective Anionic Routes to Acridones, Oxindoles, Dibenzo[b,f]azepinones, and Anthranilate Esters.
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Carbanionic Friedel—Crafts Equivalents. Regioselective Directed ortho and Remote Metalation—C—N Cross Coupling Routes to Acridones and Dibenzo[b,f]azepinones.
TL;DR: Carbanion-mediated general regioselective routes to acridones 4 and dibenzo[b,f]azepinones 20 (Table 4) are described in this paper.