Martina Spallarossa
École Polytechnique Fédérale de Lausanne
6 Papers
61 Citations
Martina Spallarossa is an academic researcher from École Polytechnique Fédérale de Lausanne. The author has contributed to research in topics: Phosphonium salt & Amide. The author has an hindex of 4, co-authored 6 publications.
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Papers
Synthesis of Vinyl Isocyanides and Development of a Convertible Isonitrile
TL;DR: (Z)-1-Bromo-2-(2-isocyanovinyl)benzene (5l) was found to be a truly universal isonitrile since, after Ugi reaction, the resulting secondary amide unit (RNHCO-) is convertible under both acidic and basic conditions.
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Enantio- and diastereoselective synthesis of highly substituted benzazepines by a multicomponent strategy coupled with organocatalytic and enzymatic procedures.
TL;DR: Enantiomerically pure 4,5-dihydro-1H-benzo[c]azepines with three contiguous stereogenic centers have been assembled by convergent strategy with good control of diastereoselectivity.
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Enantio- and Diastereoselective Synthesis of Highly Substituted Benzazepines by a Multicomponent Strategy Coupled with Organocatalytic and Enzymatic Procedures.
TL;DR: In this article, a 4,5-dihydro-1H-benzo[c]azepines with three contiguous stereogenic centers have been assembled by convergent strategy with a good control of diastereoselectivity.
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Synthesis of Vinyl Isocyanides and Development of a Convertible Isonitrile.
TL;DR: In this article, the reaction of isocyanomethylenetriphenylphosphorane, generated in situ from the corresponding phosphonium salt, with a diverse set of aldehydes, was found to be a truly universal isonitrile since, after Ugi reaction, the resulting secondary amide unit (RNHCO−) is convertible under both acidic and basic conditions.
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Passerini Reactions on Biocatalytically Derived Chiral Azetidines
Lisa Moni,Luca Banfi,Andrea Basso,Andrea Bozzano,Martina Spallarossa,Ludger A. Wessjohann,Renata Riva +6 more
TL;DR: A series of Passerini reactions on a biocatalytically derived enantiopure azetidine-2-carboxyaldehyde is explored to obtain, in a diastereoselective manner, polyfunctionalised derivatives having the potential to be cyclized to chiral bridged bicyclic nitrogen heterocycles.
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