Mark Kalaj
University of California, San Diego
38 Papers
169 Citations
Mark Kalaj is an academic researcher from University of California, San Diego. The author has contributed to research in topics: Uranyl & Halogen bond. The author has an hindex of 16, co-authored 35 publications. Previous affiliations of Mark Kalaj include George Washington University.
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Papers
MOF-Polymer Hybrid Materials: From Simple Composites to Tailored Architectures.
Mark Kalaj,Kyle C. Bentz,Sergio Ayala,Joseph M. Palomba,Kyle S Barcus,Yuji Katayama,Yuji Katayama,Seth M. Cohen +7 more
TL;DR: This Review highlights the development and recent advances in the synthesis of MOF-polymer mixed-matrix membranes (MMMs) and applications of these MMMs in gas and liquid separations and purifications, including aqueous applications such as dye removal, toxic heavy metal sequestration, and desalination.
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Postsynthetic Modification: An Enabling Technology for the Advancement of Metal-Organic Frameworks
Mark Kalaj,Seth M. Cohen +1 more
TL;DR: Both covalent and coordinative PSM have been used to create hierarchal MOFs, MOF-based porous liquids, and other unusual MOF materials, and the view on future directions of the field is highlighted.
Nylon-MOF Composites through Postsynthetic Polymerization.
TL;DR: In this article, a simple, scalable, bench-top approach to covalently tethered nylon-MOF polymer composite materials through an interfacial polymerization technique was presented, which demonstrated nearly an order of magnitude higher catalytic activity for the breakdown of a chemical warfare simulant (dimethyl-4-nitrophenyl phosphate, DMNP) compared to MOFs that are non-covalently, physically entrapped in nylon, thus highlighting the importance of MOF-polymer hybridization.
160
Self-Assembly of Metal-Organic Framework (MOF) Nanoparticle Monolayers and Free-Standing Multilayers.
TL;DR: Self-assembled MOF monolayers (SAMMs) were assembled at a liquid-air interface to produce films that are 87 wt% (89 vol%) MOF and retain the crystallinity and porosity of the MOF particles.
106
An Exceptionally Stable Metal-Organic Framework Constructed from Chelate-Based Metal-Organic Polyhedra.
Jerika A. Chiong,Jie Zhu,Jake B. Bailey,Mark Kalaj,Rohit H. Subramanian,Wenqian Xu,Seth M. Cohen,F. Akif Tezcan +7 more
TL;DR: Fe-HAF-1 presents a new addition to a small group of chelate-based MOFs and provides a rare framework whose 3D connectivity is exclusively formed by metal-hydroxamate coordination, resulting in efficient separation of organic dyes and other charged species in a size-selective fashion.
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