Mark D. Trone
North Carolina State University
6 Papers
278 Citations
Mark D. Trone is an academic researcher from North Carolina State University. The author has contributed to research in topics: Micellar electrokinetic chromatography & Solvation. The author has an hindex of 6, co-authored 6 publications.
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Papers
Congeneric behavior in estimations of octanol-water partition coefficients by micellar electrokinetic chromatography.
TL;DR: Linear Solvation Energy Relationships (LSERs) are used to explain the congeneric behavior observed when using Micellar Electrokinetic Chromatography (MEKC) to estimate the octanol-water partition coefficient scale of solute hydrophobicity.
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Characterization of chemical selectivity in micellar electrokinetic chromatography. 4. Effect of surfactant headgroup.
Mark D. Trone,Morteza G. Khaledi +1 more
TL;DR: The results suggest that the hydrogen-bond-accepting ability for surfactants is inversely proportional to the proton acidity of its headgroup.
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Statistical evaluation of linear solvation energy relationship models used to characterize chemical selectivity in micellar electrokinetic chromatography.
Mark D. Trone,Morteza G. Khaledi +1 more
TL;DR: The revised model and parameters have been found to yield a statistically better fit of the MEKC retention data as well as providing more chemically sound LSER coefficients.
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Characterization of chemical selectivity in micellar electrokinetic chromatography. VI. Effects of surfactant counter-ion.
TL;DR: In this paper, the influence of counter-ions on selectivity in micellar electrokinetic chromatography was evaluated and it was determined that selectivity differences are dependent on the valency of the counter-ion but not the type of counterion.
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Influence of ester and amide-containing surfactant headgroups on selectivity in micellar electrokinetic chromatography.
Mark D. Trone,Morteza G. Khaledi +1 more
TL;DR: While both the solute size and hydrogen bond accepting ability were found to be the most important factors in solute retention, the hydrogen bonding characteristic of the solutes have the largest influence on selectivity differences between surfactants.
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