Marius Schakel
VU University Amsterdam
90 Papers
1.1K Citations
Marius Schakel is an academic researcher from VU University Amsterdam. The author has contributed to research in topics: Phosphinidene & Ring (chemistry). The author has an hindex of 23, co-authored 90 publications. Previous affiliations of Marius Schakel include Utrecht University.
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Papers
Phosphepines: convenient access to phosphinidene complexes.
Mark L. G. Borst,Rosa E. Bulo,Christiaan W. Winkel,Daniele J. Gibney,Andreas W. Ehlers,Marius Schakel,Martin Lutz,A. L. Spek,Koop Lammertsma +8 more
TL;DR: Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes that can be trapped in high yield by alkenes, alkynes, and alcohols.
Synthesis of Novel Terminal Iridium Phosphinidene Complexes
TL;DR: Stable, crystalline iridium-complexed phosphinidenes, Cp*(L)IrPR, are readily synthesized by using LiPHMes* and dehydrohalogenation of Cp(PH2R)IrCl2 (5, R = Mes*, Is, Mes) with in situ capturing of transient Cp*,Ir⋮PR (4) with phosphines, phosphites, arsines, isocyanides, and carbon monoxide as mentioned in this paper.
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Synthesis and Reactions of Terminal Osmium and Ruthenium Complexed Phosphinidenes [(η6-Ar)(L)MPMes*]
TL;DR: In this article, very stable ruthenium and osmium containing terminal phosphinidene complexes were obtained by dehydrohalogenation in the presence of a stabilizing ligand.
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Electronic structure and stability of pentaorganosilicates.
TL;DR: The exceptional stability of recently reported pentaorganosilicates is investigated by bond energy analyses, which reconfirm that the axial bonds are more prone to heterolytic cleavage than are the equatorial bonds.
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Olefin Cycloadditions of the Electrophilic Phosphinidene Complex [iPr2N−P=Fe(CO)4]
Jan B. M. Wit,Gerno T. van Eijkel,Franciscus J. J. de Kanter,Marius Schakel,Andreas W. Ehlers,Martin Lutz,Anthony L. Spek,Koop Lammertsma +7 more
TL;DR: In this article, high-strained methylenephosphiranes are formed in the reaction of the new electrophilic phosphinidene complex [iPr(2)N-P=Fe(CO)(4)] with allenes.
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