There is, I think, something ethereal about i —the square root of minus one. I remember first hearing about it at school. It seemed an odd beast at that time—an intruder hovering on the edge of reality.

Usually familiarity dulls this sense of the bizarre, but in the case of i it was the reverse: over the years the sense of its surreal nature intensified. It seemed that it was impossible to write mathematics that described the real world in …

I and i

Entropy is a fundamental concept in thermodynamics and statistical physics. It governs processes in physics, chemistry, and biology, and its statistical and information theoretical foundations have been supplemented by recent analyses of fluctuations in microscopic and quantum systems. This article presents a review of theoretical and experimental attempts to describe and assess entropy production in a unified manner from the quantum to the classical level.

Irreversible entropy production: From classical to quantum

We present an extensive introduction to quantum collision models (CMs), also known as repeated interactions schemes: a class of microscopic system-bath models for investigating open quantum systems dynamics whose use is currently spreading in a number of research areas. Through dedicated sections and a pedagogical approach, we discuss the CMs definition and general properties, their use for the derivation of master equations, their connection with quantum trajectories, their application in non-equilibrium quantum thermodynamics, their non-Markovian generalizations, their emergence from conventional system-bath microscopic models and link to the input-output formalism. The state of the art of each involved research area is reviewed through dedicated sections. The article is supported by several complementary appendices, which review standard concepts/tools of open quantum systems used in the main text with the goal of making the material accessible even to readers possessing only a basic background in quantum mechanics. The paper could also be seen itself as a friendly, physically intuitive, introduction to fundamentals of open quantum systems theory since most main concepts of this are treated such as quantum maps, Lindblad master equation, steady states, POVMs, quantum trajectories and stochastic Schrodinger equation.

Quantum collision models: open system dynamics from repeated interactions

Entropy production plays a fundamental role in nonequilibrium thermodynamics to quantify the irreversibility of open systems. Its positivity can be ensured for a wide class of setups, but the entropy production rate can become negative sometimes. This is often taken as an indicator of non-Markovianity. We make this link precise by showing under which conditions a negative entropy production rate implies non-Markovianity and when it does not. For a system coupled to a single heat bath, this can be established within a unified language for two setups: (i) the dynamics resulting from a coarse-grained description of a Markovian master equation and (ii) the classical Hamiltonian dynamics of a system coupled to a bath. The quantum version of the latter result is shown not to hold despite the fact that the integrated thermodynamic description is formally equivalent to the classical case. The instantaneous fixed point of a non-Markovian dynamics plays an important role in our study. Our key contribution is to provide a consistent theoretical framework to study the finite-time thermodynamics of a large class of dynamics with a precise link to its non-Markovianity.

/pdf/non-markovianity-and-negative-entropy-production-rates-4uwx2oj1bt.pdf

Non-Markovianity and negative entropy production rates.

We study the dynamics of a quantum system whose interaction with an environment is described by a collision model, i.e., the open dynamics is modeled through sequences of unitary interactions between the system and the individual constituents of the environment, termed ``ancillas,'' which are subsequently traced out. In this setting, non-Markovianity is introduced by allowing for additional unitary interactions between the ancillas. For this model, we identify the relevant system-environment correlations that lead to a non-Markovian evolution. Through an equivalent picture of the open dynamics, we introduce the notion of ``memory depth'' where these correlations are established between the system and a suitably sized memory rendering the overall system+memory evolution Markovian. We extend our analysis to show that while most system-environment correlations are irrelevant for the dynamical characterization of the process, they generally play an important role in the thermodynamic description. Finally, we show that under an energy-preserving system-environment interaction, a nonmonotonic time behavior of the heat flux serves as an indicator of non-Markovian behavior.

/pdf/system-environment-correlations-and-markovian-embedding-of-1317xzaoj1.pdf

System-environment correlations and Markovian embedding of quantum non-Markovian dynamics

We study the relationship between a (non-)Markovian evolution and the entropy production rate. We consider a system qubit in contact with a thermal bath and in addition the system is strongly coupled to an ancillary qubit. We examine the steady state properties finding that the coupling leads to effective temperatures emerging in the composite system, and show that this is related to the creation of correlations between the qubits. By establishing the conditions under which the system reaches thermal equilibrium with the bath despite undergoing a non-Markovian evolution, we examine the entropy production rate, showing that its transient negativity is a sufficient sign of non-Markovianity.

Entropy production in a controlled non-Markovian setting

Using the paradigm of information backflow to characterize a non-Markovian evolution, we introduce so-called precursors of non-Markovianity, i.e. necessary properties that the system and environment state must exhibit at earlier times in order for an ensuing dynamics to be non-Markovian. In particular, we consider a quantitative framework to assess the role that established system-environment correlations together with changes in environmental states play in an emerging non-Markovian dynamics. By defining the relevant contributions in terms of the Bures distance, which is conveniently expressed by means of the quantum state fidelity, these quantities are well defined and easily applicable to a wide range of physical settings. We exemplify this by studying our precursors of non-Markovianity in discrete and continuous variable non-Markovian collision models.

Precursors of non-Markovianity

We study the relationship between (non-)Markovian evolutions, established correlations, and the entropy production rate. We consider a system qubit in contact with a thermal bath and in addition the system is strongly coupled to an ancillary qubit. We examine the steady-state properties finding that the coupling leads to effective temperatures emerging in the composite system, and show that this is related to the creation of correlations between the qubits. By establishing the conditions under which the system reaches thermal equilibrium with the bath despite undergoing a non-Markovian evolution, we examine the entropy production rate, showing that its transient negativity is a sufficient sign of non-Markovianity.

/pdf/entropy-production-and-correlations-in-a-controlled-non-15xf85w599.pdf

Entropy production and correlations in a controlled non-Markovian setting

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Entropy production in a controlled non-Markovian setting

Precursors of non-Markovianity

Entropy production and correlations in a controlled non-Markovian setting

Precursors of non-Markovianity