Magnetic and reusable MgO/MgFe2O4 nanocatalyst for biodiesel production from sunflower oil: Influence of fuel ratio in combustion synthesis on catalytic properties and performance

In this study, we designed and successfully prepared all solid state 2D/3D/2D rGO/Fe2O3/g-C3N4 nanocomposite by embedding 3D Fe2O3 nanoparticles on 2D g-C3N4 nanosheets to for 3D/2D Fe2O3/g-C3N4 followed by the addition of 2D rGO nanosheets via a simple hydrothermal technique with the support of response surface methodology for the first time. The formation of this unique 2D/3D/2D heterojunction leads to generate several nanochannels in their interfacial contact for high-speed photoinduced charge transfer. The considerable enhancement in photoinduced charge transportation and migration efficiency resulted in significant visible-light-driven degradation of emerging pharmaceutical condemnations. The 3D/2D Fe2O3/g-C3N4 nanocomposite was optimized by various concentrations of Fe2O3 in g-C3N4, followed by the optimization of rGO concentration in 2D/3D/2D rGO/Fe2O3/g-C3N4 nanocomposite to obtain maximum degradation efficiency. We observed that the 3% of rGO in 4% Fe2O3/g-C3N4 nanocomposite exhibited superior photocatalytic ability, nearly 22 times and 16 times higher than pristine g-C3N4 nanosheets towards tetracycline and ciprofloxacin degradation, respectively. The synergistic effect between 2D/3D/2D g- rGO/Fe2O3/g-C3N4 nanocomposites and the photocatalytic mechanism was well studied through various characterization techniques like XRD, FTIR, SEM-EDX-mapping, HR-TEM, UV–vis DRS, PL, XPS and EPR. In addition, the 2D/3D/2D rGO/Fe2O3/g-C3N4 nanocomposite exhibits excellent recyclability and stability, establishing a promising application in environmental remediation. This research would provide a noteworthy platform for the extensive photocatalytic properties of 2D/3D/2D heterojunction nanocomposite system with enhanced charge migration and separation.

Computationally guided synthesis of (2D/3D/2D) rGO/Fe2O3/g-C3N4 nanostructure with improved charge separation and transportation efficiency for degradation of pharmaceutical molecules

As the global water shortage becomes increasingly serious, it is highly imperative to develop efficient, renewable, and large-scale water purification devices. Herein, an efficient solar-driven water purification device of wood coated with Fe2O3 nanoparticle-decorated carbon nanotubes (Fe2O3/CNT) is fabricated in only a few seconds by one-step combustion of ferric acetylacetonate in an ambient environment. The thin layer of the Fe2O3/CNT hybrid coated on the upper surface of the wood serves as a solar-light absorber for converting solar energy to thermal energy, while the thermally insulating wood layer with vertically aligned channels endows the device with rapid water upward transport and localizes the generated heat inside the Fe2O3/CNT layer for solar-driven water evaporation. As a result, the wood/Fe2O3/CNT device achieves a high water steam generation capability of 1.42 kg m-2 h-1 along with an excellent evaporation efficiency of 87.2% under 1 sun irradiation, higher than most of the wood-based solar-driven water evaporation device reported. This device is also efficient in the purification of seawaters and wastewaters. This work demonstrates a rapid and facile methodology for large-scale fabrication of wood/Fe2O3/CNT devices for efficient solar-driven water purification.

Coating of Wood with Fe2O3-Decorated Carbon Nanotubes by One-Step Combustion for Efficient Solar Steam Generation.

Development of porous, antibacterial and biocompatible GO/n-HAp/bacterial cellulose/β-glucan biocomposite scaffold for bone tissue engineering

Synergistic deep removal of As(III) and Cd(II) by a calcined multifunctional MgZnFe-CO3 layered double hydroxide: Photooxidation, precipitation and adsorption.

Enhanced nonlinear optical absorption and optical limiting properties of superparamagnetic spinel zinc ferrite decorated reduced graphene oxide nanostructures

Nanohybrids consisting of uniform nanospheres and nanospindles of zinc ferrite attached to reduced graphene oxide were prepared by hydrothermal reaction. Zinc ferrite decorated reduced graphene oxide exhibited enhanced nonlinear absorption, refraction and optical limiting (OL) action under continuous wave (532 nm, 50 mW) and ultrafast (800 nm, 150 fs) excitation. The enhancement can possibly be attributed to the synergistic effect stemming from the observed reverse saturable absorption and self-defocusing in the material. The role of defects in improving the nonlinear optical (NLO) performance of ZnFe2O4–rGO was explained with the aid of Raman spectroscopy and ground state absorption studies. Using fs and cw excitation, the estimated nonlinear absorption coefficient [γ3PA(fs) = 4.0 × 10−12 m W−1, β(cw) = 6.5 × 10−5 m W−1], nonlinear refractive index [n2(fs) = 4.2 × 10−18 m2 W−1, n2(cw) = 4.7 × 10−12 m2 W−1] and third order nonlinear optical (NLO) susceptibility [χ (3) (fs) = 1.9 × 10−15 esu, χ (3) (cw) = 4.2 × 10−6 esu] of nanospindle ZnFe2O4–rGO were found to be higher than those of its other counter parts. The estimated NLO parameters were found to be higher than those of other known OL materials such as functionalized hydrogen exfoliated graphene, CdO. Thus zinc ferrite decorated rGO nanostructures with proficient NLO coefficients have potential scope for utilizing them as smart materials for OL applications.

Improved third-order optical nonlinearity and optical limiting behaviour of (nanospindle and nanosphere) zinc ferrite decorated reduced graphene oxide under continuous and ultrafast laser excitation

Nonlinear optical absorption and optical limiting properties of cadmium ferrite

Third-order nonlinear optical response of heat-treated magnesium ferrite (MgFe2O4) synthesized by simple combustion was studied by Z-scan experiment under continuous wave laser excitation (532 nm, 50 mW). Powder XRD patterns confirm the single-phase formation of spinel structure MgFe2O4 with cubic symmetry. Estimation of crystallite size from XRD data shows a decrease in size as annealing temperature increases. In the FTIR spectra, two absorption bands around 400 and 600 cm−1 correspond to the octahedral and tetrahedral sites of Fe–O and Mg–O, respectively. FESEM analysis pictures the presence of micro-grained particle with porous structure. Single-beam Z-scan experiment shows that the samples possess saturable absorption and self-defocusing nature. The third-order nonlinear optical properties calculated from the experimental data were consistent with the values predicted by theoretical fit. Estimated third-order nonlinear optical susceptibility, χ(3), was found to be increasing with increase in annealing temperature. The samples exhibit limiting behavior beyond 14.5 mW, and the corresponding output value gets clamped at 1.79, 1.95, and 2.54 mW. Magnesium ferrite treated at 900 °C with higher nonlinear optical susceptibility can be used as a potential candidate for low power limiting applications.

Third-order nonlinear optical properties and power limiting behavior of magnesium ferrite under CW laser (532 nm, 50 mW) excitation

Broadband optical limiting and wavelength-dependent nonlinear absorption studies of Au-Fe2O3-(15, 25, 40 wt %)rGO (reduced graphene oxide) nanocomposites were investigated using the Z-scan technique and excited with femtosecond (700–900 nm, 80 MHz, 150 fs) laser pulses. A reduction in the graphene perfect (La) domain and ID/IG ratio observed in the Raman data and the appearance of a Au 4f and Fe 2p singlet along with a shift in the C 1s state toward higher energy in the XPS data, peak broadening in the XRD data, and different mass residues left out with respect to content of rGO in the TG-DTA data strongly indicated the incorporation of Au-Fe2O3 nanostructures on solar exfoliated reduced graphene oxide. Selected aread electron diffraction data ascertained the presence of Au and Fe2O3 as a composite, and transmission electron microscopy (TEM) data revealed that the nano-octahedra Au-Fe2O3 turned themselves into nanospindles during incorporation of rGO. Ground state absorption spectra illustrated a pure and...

Wavelength-Dependent Nonlinear Optical Absorption and Broadband Optical Limiting in Au-Fe2O3-rGO Nanocomposites

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