Linjie Li
Sichuan University
18 Papers
109 Citations
Linjie Li is an academic researcher from Sichuan University. The author has contributed to research in topics: Enol & Silylation. The author has an hindex of 8, co-authored 18 publications.
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Papers
Recent Advances in C–Si Bond Activation via a Direct Transition Metal Insertion
TL;DR: In this paper, the C-Si bond activation via a direct transition metal insertion has recently gained growing attention in the organic chemical community, and the process not only shows a new and unique entry to functionalize the C−Si bond, but also presents a powerful method to synthesize diverse organosilanes via formation of a new C −Si bond.
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3-Silaazetidine: An Unexplored yet Versatile Organosilane Species for Ring Expansion toward Silaazacycles.
TL;DR: 3-Silaazetidine as discussed by the authors is a unique small ring silacycle bearing silicon and nitrogen atoms, which has not been adequately explored due to the lack of a general synthetic scheme and its sensitivity to air.
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Sakurai Reaction of 3,3-Bis(silyl) Silyl Enol Ethers with Acetals Involving Selective Desilylation of the Geminal Bis(silane). Concise Synthesis of Nematocidal Oxylipid
TL;DR: 3,3-Bis(silyl) silyl enol ethers have been shown to exhibit predominantly Sakurai reactivity, rather than Mukaiyama aldol reactivity in their Lewis acid promoted reactions with acetals, demonstrating the attractive bifunctionality of geminal bis(silanes.
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Efficient approach to 3,3-bissilyl carbonyl and enol derivatives via retro-[1,4] brook rearrangement of 3-silyl allyloxysilanes.
TL;DR: A facile and highly stereoselective retro-[1,4] Brook rearrangement of 3-silyl allyloxysilanes has been discovered and can be used to produce the synthetically useful 1,2-diol diastereoselectively.
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Addition of TMS-substituted oxiranyl anions to acylsilanes. A highly stereoselective approach to tetrasubstituted (Z)-β-hydroxy-α-TMS silyl enol ethers.
TL;DR: A highly stereoselective approach to novel tetrasubstituted (Z)-β-hydroxy-α-TMS silyl enol ethers is described, which proceeds via a sequential addition/[1,2]-Brook rearrangement/epoxide-opening process of TMS-substituting oxiranyl anions with acylsilanes.
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