There is, I think, something ethereal about i —the square root of minus one. I remember first hearing about it at school. It seemed an odd beast at that time—an intruder hovering on the edge of reality.

Usually familiarity dulls this sense of the bizarre, but in the case of i it was the reverse: over the years the sense of its surreal nature intensified. It seemed that it was impossible to write mathematics that described the real world in …

I and i

Energy production and storage technologies have attracted a great deal of attention for day-to-day applications. In recent decades, advances in lithium-ion battery (LIB) technology have improved living conditions around the globe. LIBs are used in most mobile electronic devices as well as in zero-emission electronic vehicles. However, there are increasing concerns regarding load leveling of renewable energy sources and the smart grid as well as the sustainability of lithium sources due to their limited availability and consequent expected price increase. Therefore, whether LIBs alone can satisfy the rising demand for small- and/or mid-to-large-format energy storage applications remains unclear. To mitigate these issues, recent research has focused on alternative energy storage systems. Sodium-ion batteries (SIBs) are considered as the best candidate power sources because sodium is widely available and exhibits similar chemistry to that of LIBs; therefore, SIBs are promising next-generation alternatives. Recently, sodiated layer transition metal oxides, phosphates and organic compounds have been introduced as cathode materials for SIBs. Simultaneously, recent developments have been facilitated by the use of select carbonaceous materials, transition metal oxides (or sulfides), and intermetallic and organic compounds as anodes for SIBs. Apart from electrode materials, suitable electrolytes, additives, and binders are equally important for the development of practical SIBs. Despite developments in electrode materials and other components, there remain several challenges, including cell design and electrode balancing, in the application of sodium ion cells. In this article, we summarize and discuss current research on materials and propose future directions for SIBs. This will provide important insights into scientific and practical issues in the development of SIBs.

/pdf/sodium-ion-batteries-present-and-future-gf1bd0vhq4.pdf

Sodium-ion batteries: present and future

Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries

Since its first isolation in 2004, graphene has become one of the hottest topics in the field of materials science, and its highly appealing properties have led to a plethora of scientific papers. Among the many affected areas of materials science, this 'graphene fever' has influenced particularly the world of electrochemical energy-storage devices. Despite widespread enthusiasm, it is not yet clear whether graphene could really lead to progress in the field. Here we discuss the most recent applications of graphene - both as an active material and as an inactive component - from lithium-ion batteries and electrochemical capacitors to emerging technologies such as metal-air and magnesium-ion batteries. By critically analysing state-of-the-art technologies, we aim to address the benefits and issues of graphene-based materials, as well as outline the most promising results and applications so far.

The role of graphene for electrochemical energy storage

The science and technology of ultracapacitors are reviewed for a number of electrode materials, including carbon, mixed metal oxides, and conducting polymers. More work has been done using microporous carbons than with the other materials and most of the commercially available devices use carbon electrodes and an organic electrolytes. The energy density of these devices is 3¯5 Wh/kg with a power density of 300¯500 W/kg for high efficiency (90¯95%) charge/discharges. Projections of future developments using carbon indicate that energy densities of 10 Wh/kg or higher are likely with power densities of 1¯2 kW/kg. A key problem in the fabrication of these advanced devices is the bonding of the thin electrodes to a current collector such the contact resistance is less than 0.1 cm2. Special attention is given in the paper to comparing the power density characteristics of ultracapacitors and batteries. The comparisons should be made at the same charge/discharge efficiency.

Ultracapacitors: Why, How, and Where is the Technology

Encapsulating sulfur in δ-MnO2 at room temperature for Li-S battery cathode

Electrochemical water splitting is a fascinating technology for sustainable hydrogen production, and electrocatalysts are essential to accelerate the sluggish hydrogen and oxygen evolution reactions (HER and OER). Transition-metal-based electrocatalysts have attracted enormous interests due to the abundant resources, low cost, and comparable catalytic performance to noble metals. Among these studies, fibrous materials possess distinct advantages, such as unique structure, high active surface area, and fast electron transport. Herein, the most recent progress of nanofiber electrocatalysts on synthesis and application in HER and OER is summarized, with emphasis on iron-, cobalt-, and nickel-based materials. Moreover, the challenge and prospects of fibrous-structured electrocatalysts on water splitting is provided.

Transition-Metal (Fe, Co, and Ni)-Based Nanofiber Electrocatalysts for Water Splitting

Electrochemical devices, as renewable and clean energy systems, display a great potential to meet the sustainable development in the future However, well-designed and highly efficient electrocatalysts are the technological dilemmas that retard their practical applications Metal-organic frameworks (MOFs) derived electrocatalysts exhibit tunable structure and intriguing activity and have received intensive investigation in recent years In this review, the recent progress of MOFs-derived carbon-based single atoms (SAs) and metal nanoparticles (NPs) catalysts for energy-related electrocatalysis is summarized The effects of synthesis strategy, coordination environment, morphology, and composition on the catalytic activity are highlighted Furthermore, these SAs and metal NPs catalysts for the applications of electrocatalysis (hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, carbon dioxide reduction reaction, and nitrogen reduction reaction) are overviewed Finally, some current challenges and foresighted ideas for MOFs-derived carbon-based metal electrocatalysts are presented

MOFs-Derived Carbon-Based Metal Catalysts for Energy-Related Electrocatalysis.

Rechargeable aqueous zinc/vanadium pentoxide (Zn/V2O5) battery chemistry has recently attracted a great attention due to its high safety, material abundance, cost effectiveness, and desirable energ...

Long-Life Zinc/Vanadium Pentoxide Battery Enabled by a Concentrated Aqueous ZnSO4 Electrolyte with Proton and Zinc Ion Co-Intercalation

Promoted synergy in core-branch CoP@NiFe–OH nanohybrids for efficient electrochemical-/ photovoltage-driven overall water splitting

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