Soil improvement using biopolymers has attracted considerable attention in recent years, with the aim to reduce the harmful environmental effects of traditional materials, such as cement. This paper aims to provide a review on the environmental assessment of using biopolymers as binders in soil improvement, biopolymer-treated soil characteristics, as well as the most important factors affecting the behavior of the treated soil. In more detail, environmental benefits and concerns about the use of biopolymers in soil improvement as well as biopolymer–soil interaction are discussed. Various geotechnical properties are evaluated and compared, including the unconfined compressive strength, shear strength, erosion resistance, physical properties, and durability of biopolymer-treated soils. The influential factors and soil and environmental conditions affecting various geotechnical characteristics of biopolymer-treated soils are also discussed. These factors include biopolymer concentration in the biopolymer–soil mixture, moisture condition, temperature, and dehydration time. Potential opportunities for biopolymers in geotechnical engineering and the challenges are also presented.

Biopolymers as Green Binders for Soil Improvement in Geotechnical Applications: A Review

Sustainable engineering discourages the use of conventional soil stabilizers such as lime and cement owing to their higher carbon emission rates. To address these challenges, many researchers considered biopolymer stabilization, a promising green technique in geotechnical engineering practice for treating expansive soils. This study evaluated the performance of two biopolymers, xanthan gum (XG) and guar gum (GG), in improving the unconfined compressive strength (UCS) and consolidation characteristics of an expansive soil subjected to different testing conditions. The dosage of the biopolymers (XG and GG) was maintained at 0.5%, 1%, 2%, and 4% by weight of dry mass of soil mass. Biopolymer treated samples were subjected to desiccator and natural curing conditions (i.e., specimens were exposed to different temperature and relative humidity conditions) for 7, 14, 28, 45, and 60 days. Results showed that the UCS of biopolymer-treated soil increased with increased dosage up to 2% and 1% for XG and GG, respectively; strength significantly improved during the first 28 days of curing under controlled conditions. Improvement of strength was due to increased adhesive strength between gum strands and soil particles. One-dimensional fixed-ring oedometer consolidation test results indicated that the compressibility and swelling characteristics of biopolymer-treated soil increased due to the hydrophilic nature of gum and an increase in the repulsive forces between negatively charged clay particles and the respective functional groups of XG and GG. Scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR) were performed on both untreated and biopolymer-treated soil to evaluate the interaction mechanism between soil and biopolymer strands. The microlevel studies confirmed the crosslinking of soil particles by gum strands, which aids in the strength improvement. 

Effect of Biopolymeric Stabilization on the Strength and Compressibility Characteristics of Cohesive Soil

Soil amelioration is a challenging task in bulk civil engineering applications such as embankment slopes, landfill liner, pavement subgrade, retaining wall back fill. The conventional chemical stabilization techniques (i.e., cement, calcium hydroxide, sodium chloride, calcium chloride, etc.) inherently suffer from associated carbon emissions during their production stages. With the advent of biopolymers derived from natural sources having low embodied energy levels, they can replace conventional stabilizers. The current review article highlights the significant properties of two such biopolymers, i.e., xanthan gum (XG) and guar gum (GG), and their innate potential in stabilizing different soil types including mine tailings. The issues arising with wet and dry mixing of these biopolymers and suggested measures have been critically addressed. The degradation characteristics of biopolymers, which limit their use for bulk civil engineering applications, have been critically discussed, and the potential solutions to overcome durability issues are suggested. Future applications of these biopolymers in geoenvironmental engineering relying on the metal encapsulation properties are discussed in detail. It is believed that the selected biopolymers in this review are renewable, sustainable and remarkable materials with low embodied energy levels and low carbon footprint values compared to existing conventional stabilizers.

State-of-the-art review on efficacy of xanthan gum and guar gum inclusion on the engineering behavior of soils

Abstract In the last decade, biopolymers have been used as organic soil binders in ground improvement and earthen construction material modification. Although biopolymer-treated soils have substantially enhanced mechanical strength, the deformation characteristics under external loads and material durability (e.g. biodeterioration due to microbial activity) have not yet been fully understood, which limits the in situ practical application of the biopolymer-based soil treatment technology. This study investigated the efficiency of combined carrageenan and casein in strengthening a clayey soil with the biodeterioration consideration. Both mechanical tests (e.g. unconfined compressive strength and one-dimensional consolidation) and biological tests (e.g. high throughput sequencing and rating of mould growth) were conducted. Results indicated that the usage of the carrageenan–casein mixture induced a higher soil compressive strength compared with either carrageen or casein, due to the formation of a three-dimensional gel network. In addition, carrageenan–casein mixture and casein decreased the compressibility of the clayey soil, which might be attributed to the casein’s peculiarity of self-associating into micelles, leading to minimal interactions with water molecules. Carrageenan, due to its affinity for water, increased the soil compressibility. Under the impact of microbial activity, the biopolymer-treated soils underwent deterioration in both surface appearance (i.e. coloured stains and patches caused by mould growth) and compressive strength. A linear relationship was proposed, in which a reduction in compressive strength by approximately 11% is expected while the rating of mould growth is increased by one in a five-rating system. The current research demonstrates that the soil reinforcement with combined carrageenan and casein is able to improve both soil strength and deformation behaviours. It is also suggested to take into account the biodeterioration considerations in the design and implementation of biopolymer-based soil reinforcement practices. 

/pdf/mechanical-and-biodeterioration-behaviours-of-a-clayey-soil-2isk49rr.pdf

Mechanical and biodeterioration behaviours of a clayey soil strengthened with combined carrageenan and casein

Sand–clay mixtures can be encountered in both natural soils (e.g., residual soils, clay deposits and clinosols) and artificial fills. The method of utilising biopolymers in ground improvement for sand–clay mixtures has emerged recently. However, a full understanding of the strengthening effect of biopolymer-treated sand–clay mixtures has not yet been achieved due to a limited number of relevant studies. In this study, xanthan gum (XG), as one of the eco-friendly biopolymers, was used to treat reconstituted sand–clay mixtures that had various compositions in related to clay (or sand) content and clay type (kaolin and bentonite). A series of laboratory unconfined compression strength (UCS) tests were conducted to probe the performances of XG-treated sand–clay mixtures from two aspects, i.e., optimum treatment conditions (e.g., XG content and initial moisture content) to achieve the maximum strengthening effect and strengthening efficiency for the sand–clay mixtures with different compositions. The experimental results indicated that the optimum initial moisture content decreased as the sand content increased. The optimum XG content, which also decreased with the increasing sand content, remained approximately 3.75% for all sand–kaolin mixtures and 5.75% for all sand–bentonite mixtures if calculated based on clay fraction. While untreated sand–kaolin mixtures and sand–bentonite mixtures had comparable UCS values, XG-treated sand–kaolin mixtures seemed to have better improved mechanical strength due to higher ionic (or hydrogen) bonds with XG and low-swelling properties compared with bentonite. The deformation modulus of XG-treated sand–clay mixtures were positively related with UCS. The variation in UCS and stiffness for each treatment condition increased as the sand content was elevated for both sand-kaolin and sand-bentonite mixtures. An increment in the proportion of the heterogeneous composite formed by irregular sand particles conglomerated with the XG–clay matrix in total soil might be responsible for this phenomenon.

https://www.mdpi.com/2071-1050/13/7/3732/pdf

The optimisation analysis of sand‐clay mixtures stabilised with xanthan gum biopolymers

Performance of soils enhanced with eco-friendly biopolymers in unconfined compression strength tests and fatigue loading tests

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Performance of soils enhanced with eco-friendly biopolymers in unconfined compression strength tests and fatigue loading tests

The optimisation analysis of sand‐clay mixtures stabilised with xanthan gum biopolymers