The S‐scheme heterojunctions have great potential for photocatalytic carbon dioxide reduction due to their unique carrier migration pathways, superior carrier separation efficiencies, and high redox capacities. However, the precise process of the oriented powerful electron transport remains a great challenge. Herein, an InOCd bond‐modulated S‐scheme heterojunction of In2O3/CdSe‐DETA is synthesized by a simple microwave‐assisted hydrothermal method for the accelerated photogenerated electron transfer. Meanwhile, the oxygen vacancies (Vo) of In2O3 have an electron capture effect. Consequently, thanks to the synergistic effect of this In‐Vo‐In‐O‐Cd structural units at the interface, electrons are extracted and rapidly transferred to the surface‐active sites, which improves the electronic coupling of CO2. This finding precisely adjusts the electron transfer pathway and shortens the electron transfer distance. The synergistic effect of this chemical bond established in the S‐scheme heterostructure with oxygen vacancies in In2O3 (Vo‐In2O3) provides new insights into photocatalytic CO2 reduction.

Interfacial Chemical Bond and Oxygen Vacancy‐Enhanced In2O3/CdSe‐DETA S‐scheme Heterojunction for Photocatalytic CO2 Conversion

Metal halide perovskite materials in photocatalysis: Design strategies and applications

The selective functionalization of alkanes has long been recognized as a prominent challenge and an arduous task in organic synthesis. Hydrogen atom transfer (HAT) processes enable the direct generation of reactive alkyl radicals from feedstock alkanes and have been successfully employed in industrial applications such as the methane chlorination process, etc. Nevertheless, challenges in the regulation of radical generation and reaction pathways have created substantial obstacles in the development of diversified alkane functionalizations. In recent years, the application of photoredox catalysis has provided exciting opportunities for alkane C–H functionalization under extremely mild conditions to trigger HAT processes and achieve radical-mediated functionalizations in a more selective manner. Considerable efforts have been devoted to building more efficient and cost-effective photocatalytic systems for sustainable transformations. In this perspective, we highlight the recent development of photocatalytic systems and provide our views on current challenges and future opportunities in this field.

/pdf/resurgence-and-advancement-of-photochemical-hydrogen-atom-3mpr1ito.pdf

Resurgence and advancement of photochemical hydrogen atom transfer processes in selective alkane functionalizations

Insights into the optical and electrochemical features of CuAl2O4 nanoparticles and it use for methyl violet oxidation under sunlight exposure

Advanced oxidation processes (AOPs) utilizing heterogeneous catalysts have attracted great attention in the last decade. The use of solid catalysts, including metal and metal oxide nanoparticle support materials, exhibited better performance compared with the use of homogeneous catalysts, which is mainly related to their stability in hostile environments and recyclability and reusability. Various solid supports have been reported to enhance the performance of metal and metal oxide catalysts for AOPs; undoubtedly, the utilization of clay as a support is the priority under consideration and has received intensive interest. This review provides up-to-date progress on the synthesis, features, and future perspectives of clay-supported metal and metal oxide for AOPs. The methods and characteristics of metal and metal oxide incorporated into the clay structure are strongly influenced by various factors in the synthesis, including the kind of clay mineral. In addition, the benefits of nanomaterials from a green chemistry perspective are key aspects for their further considerations in various applications. Special emphasis is given to the basic schemes for clay modifications and role of clay supports for the enhanced mechanism of AOPs. The scaling-up issue is suggested for being studied to further applications at industrial scale.

/pdf/clay-supported-metal-oxide-nanoparticles-in-catalytic-13rw59t5.pdf

Clay-Supported Metal Oxide Nanoparticles in Catalytic Advanced Oxidation Processes: A Review

Exploring photocatalysts to foster CO2 photoreduction into high value-added chemicals is of great significance. Lead halide perovskites (LHPs) have recently been extensively investigated as photocatalysts, owing to their facile fabrication and prominent optoelectronic properties. However, the toxicity of lead and instability will hinder their future large-scale applications. To address these challenges, a series of lead-free Sb-based all-inorganic mixed halide perovskite Cs3 Sb2 (Brx I1- x )9 (0 ≤ x ≤ 1) nanoplatelets (NPLs) is synthesized. The perovskite NPLs are prepared using a ligand-assisted re-precipitation approach at 50 °C. The authors observe the tunability of their optical band gaps from 2.1 to 2.5 eV, and they can maintain the excellent stability over 120 h under heating at 100 °C or UV light irradiation. The resultant materials are employed as efficient photocatalysts for visible-light driven CO2 reduction at the gas-solid interface. The Cs3 Sb2 (Br0.7 I0.3 )9 perovskite NPLs afford an impressive overall yield of 27.7 µmol g-1 for the selective photocatalytic conversion of CO2 into CO. This study represents a significant demonstration for practical artificial photosynthesis by using LHP materials as photocatalysts.

Synthesis of Stable Lead-Free Cs3 Sb2 (Brx I1- x )9 (0 ≤ x ≤ 1) Perovskite Nanoplatelets and Their Application in CO2 Photocatalytic Reduction.

Chloride oxidation has tremendous utility in the burgeoning field of chlorine-mediated C-H activation, yet it remains a challenging process to initiate with light because of the exceedingly positive one-electron reduction potential, E° (Cl•/-), beyond most common transition-metal photooxidants. Herein, two photocatalytic chloride oxidation pathways that involve either one- or consecutive two-photon excitation of N-phenylphenothiazine (PTH) are presented. The one-photon pathway generates PTH•+ by oxidative quenching that subsequently disproportionates to yield PTH2+ that oxidizes chloride; this pathway is also accessed by the electrochemical oxidation of PTH. The two-photon pathway, which proceeded through the radical cation excited state, 2PTH•+*, was of particular interest as this super-photooxidant was capable of directly oxidizing chloride to chlorine atoms. Laser flash photolysis revealed that the photooxidation by the doublet excited state proceeded on a subnanosecond timescale through a static quenching mechanism with an ion-pairing equilibrium constant of 0.36 M-1. The PTH photoredox chemistry was quantified spectroscopically on nanosecond and longer time scales, and chloride oxidation chemistry was revealed by reactivity studies with model organic substrates. One- and two-photon excitation of PTH enabled chlorination of unactivated C(sp3)-H bonds of organic compounds such as cyclohexane with substantial yield enhancement observed from inclusion of the second excitation wavelength. This study provides new mechanistic insights into chloride oxidation catalyzed by an inexpensive and commercially available organic photooxidant.

Chloride Oxidation by One- or Two-Photon Excitation of N-Phenylphenothiazine.

Preparation and photocatalytic properties of Bi-doped TiO2/montmorillonite composite

Atomically precise gold nanoclusters (Au NCs) have high specific surface area and abundant unsaturated active sites. Traditionally, Au NCs are employed as thermocatalysts for multielectron transfer redox catalysis. Meanwhile, Au NCs also exhibit discrete energy levels, tunable photophysical and electrochemical properties, including visible to near infrared absorption, microsecond long-lived excited-state lifetime, and redox chemistry. In recent years, Au NCs are increasingly employed as visible to near infrared photocatalysts for their high photocatalytic activity and unique selectivity. This review focuses on the photophysical properties of a variety of Au NCs and their employment as photocatalysts in photocatalytic reactions and related applications including solar energy conversion and photodynamic therapies.

/pdf/gold-nanoclusters-photophysical-properties-and-28dy0dbq.pdf

Gold nanoclusters: Photophysical properties and photocatalytic applications

Efficient oxidation of ammonium to nitrogen gas via accelerated ClO• generation at TiO2/Ru-IrO2 bifacial electrode in a UV-driven photoelectrochemical system

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Synthesis of Stable Lead-Free Cs3 Sb2 (Brx I1- x )9 (0 ≤ x ≤ 1) Perovskite Nanoplatelets and Their Application in CO2 Photocatalytic Reduction.

Chloride Oxidation by One- or Two-Photon Excitation of N-Phenylphenothiazine.

Preparation and photocatalytic properties of Bi-doped TiO2/montmorillonite composite

Gold nanoclusters: Photophysical properties and photocatalytic applications

Efficient oxidation of ammonium to nitrogen gas via accelerated ClO• generation at TiO2/Ru-IrO2 bifacial electrode in a UV-driven photoelectrochemical system