Kandasamy Jeyakumar
Indian Institute of Technology Madras
17 Papers
140 Citations
Kandasamy Jeyakumar is an academic researcher from Indian Institute of Technology Madras. The author has contributed to research in topics: Catalysis & Aldehyde. The author has an hindex of 8, co-authored 16 publications.
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Papers
Selective oxidation of sulfides to sulfoxides and sulfones at room temperature using H2O2 and a Mo(VI) salt as catalyst
TL;DR: In this article, selective oxidation of sulfides to sulfoxides and sulfones is achieved by H 2 O 2 using MoO 2 Cl 2 as the catalyst, and various substituted sulfides having functional groups such as methyl, methoxy, bromo, nitro, alkene, alkyne, alcohol, ester, aldehyde and an oxime are successfully and selectively oxidized without affecting the sensitive functionalities.
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Application of molybdenum(VI) dichloride dioxide (MoO2Cl2) in organic transformations
TL;DR: In this paper, the role of MoO2Cl2 and some complexes containing MoO 2Cl2 as catalysts for various Lewis acid catalysed organic transformations, oxidation and reduction reactions is reviewed.
Copper perchlorate: Efficient acetylation catalyst under solvent free conditions
TL;DR: The transition metal perchlorates used in this article were found to be more efficient than the already reported metal triflates and s, p-block per-chlorates.
38
Self-Assembly by Ligand-Exchange Reactions
TL;DR: In this article, an interesting phenomenon of ligand exchange is observed in the DMSO solution of certain self-assembled molecules generated from cis-protected PdII and organic ligands.
29
Aerobic oxidation of benzyl alcohols by MoVI compounds
TL;DR: In this article, a selective and controlled aerobic oxidation of activated benzyl alcohols to the corresponding aldehydes is achieved in refluxing CH3CN using catalytic amounts of MoO2Cl2(L)2 where L is DMSO, DMF or THF.
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