Chitin, a fascinating biopolymer found in living organisms, fulfills current demands of availability, sustainability, biocompatibility, biodegradability, functionality, and renewability. A feature of chitin is its ability to structure into hierarchical assemblies, spanning the nano- and macroscales, imparting toughness and resistance (chemical, biological, among others) to multicomponent materials as well as adding adaptability, tunability, and versatility. Retaining the inherent structural characteristics of chitin and its colloidal features in dispersed media has been central to its use, considering it as a building block for the construction of emerging materials. Top-down chitin designs have been reported and differentiate from the traditional molecular-level, bottom-up synthesis and assembly for material development. Such topics are the focus of this Review, which also covers the origins and biological characteristics of chitin and their influence on the morphological and physical-chemical properties. We discuss recent achievements in the isolation, deconstruction, and fractionation of chitin nanostructures of varying axial aspects (nanofibrils and nanorods) along with methods for their modification and assembly into functional materials. We highlight the role of nanochitin in its native architecture and as a component of materials subjected to multiscale interactions, leading to highly dynamic and functional structures. We introduce the most recent advances in the applications of nanochitin-derived materials and industrialization efforts, following green manufacturing principles. Finally, we offer a critical perspective about the adoption of nanochitin in the context of advanced, sustainable materials.

Nanochitin: Chemistry, Structure, Assembly, and Applications

Biobased nanomaterials have gained growing interest in recent years for the sustainable development of composite films and coatings, providing new opportunities and high-performance products. In particular, chitin and cellulose nanocrystals offer an attractive combination of properties, including a rod shape, dispersibility, outstanding surface properties, and mechanical and barrier properties, which make these nanomaterials excellent candidates for sustainable reinforcing materials. Until now, most of the research has been focused on cellulose nanomaterials; however, in the last few years, chitin nanocrystals (ChNCs) have gained more interest, especially for biomedical applications. Due to their biological properties, such as high biocompatibility, biodegradability, and antibacterial and antioxidant properties, as well as their superior adhesive properties and promotion of cell proliferation, chitin nanocrystals have emerged as valuable components of composite biomaterials and bioactive materials. This review attempts to provide an overview of the use of chitin nanocrystals for the development of bioactive composite films in biomedical and packaging systems.

/pdf/chitin-nanocrystals-environmentally-friendly-materials-for-166ytmae.pdf

Chitin Nanocrystals: Environmentally Friendly Materials for the Development of Bioactive Films

Natural nano-fillers materials for the Bio-composites: A review

Ionic liquids (ILs) have been shown to efficiently dissolve substrates with poor solubility. In particular, they act as powerful solvents for structural polysaccharides, which are difficult to dissolve using conventional...

/pdf/application-of-ionic-liquids-for-the-functional-2yvsr4qo.pdf

Application of ionic liquids for the functional materialization of chitin

Although chitin is a representative abundant polysaccharide, it is mostly unutilized as a material source because of its poor solubility and processability. Certain specific properties, such as biodegradability, biocompatibility, and renewability, make nanofibrillation an efficient approach for providing chitin-based functional nanomaterials. The composition of nanochitins with other polymeric components has been efficiently conducted at the nanoscale to fabricate nanostructured composite materials. Disentanglement of chitin microfibrils in natural sources upon the top-down approach and regeneration from the chitin solutions/gels with appropriate media, such as hexafluoro-2-propanol, LiCl/N, N-dimethylacetamide, and ionic liquids, have, according to the self-assembling bottom-up process, been representatively conducted to fabricate nanochitins. Compared with the former approach, the latter one has emerged only in the last one-and-a-half decade. This short review article presents the preparation of composite materials from the self-assembled chitin nanofibers combined with other polymeric substrates through regenerative processes based on the bottom-up approach.

Preparation of Composite Materials from Self-Assembled Chitin Nanofibers.

In this study, we investigate the Pickering emulsion polymerization of styrene using scaled-down chitin nanofibers (SD-ChNFs) as stabilizers to produce nanochitin/polystyrene composite particles. Prior to emulsion polymerization, an SD-ChNF aqueous dispersion was prepared by disintegrating bundles of the parent ChNFs with an upper hierarchical scale in aqueous acetic acid through ultrasonication. After styrene was added to the resulting dispersions, the mixtures at the desired weight ratios (SD-ChNFs to styrene = 0.1:1–1.4:1) were ultrasonicated to produce Pickering emulsions. Radical polymerization was then conducted in the presence of potassium persulfate as an initiator in the resulting emulsions to fabricate the composite particles. The results show that their average diameters decreased to a minimum of 84 nm as the weight ratios of SD-ChNFs to styrene increased. The IR and 1H-NMR spectra of the composite particle supported the presence of both chitin and polystyrene in the material.

Preparation of Nanochitin/Polystyrene Composite Particles by Pickering Emulsion Polymerization Using Scaled-Down Chitin Nanofibers

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Preparation of Nanochitin/Polystyrene Composite Particles by Pickering Emulsion Polymerization Using Scaled-Down Chitin Nanofibers