Structured adsorbents, especially in the form of monolithic contactors, offer an excellent gas–solid contacting strategy for the development of practical and scalable CO2 capture technologies. In this study, the fabrication of three-dimensional (3D)-printed 13X and 5A zeolite monoliths with novel structures and their use in CO2 removal from air are reported. The physical and structural properties of these printed monoliths are evaluated and compared with their powder counterparts. Our results indicate that 3D-printed monoliths with zeolite loadings as high as 90 wt % exhibit adsorption uptake that is comparable to that of powder sorbents. The adsorption capacities of 5A and 13X monoliths were found to be 1.59 and 1.60 mmol/g, respectively, using 5000 ppm (0.5%) CO2 in nitrogen at room temperature. The dynamic CO2/N2 breakthrough experiments show relatively fast dynamics for monolithic structures. In addition, the printed zeolite monoliths show reasonably good mechanical stability that can eventually preve...

3D-Printed Zeolite Monoliths for CO2 Removal from Enclosed Environments

Amine-functionalized metal–organic frameworks (MOFs) are facile adsorbents for CO2 removal from enclosed environments. In this study, we prepared polyethylenimine (PEI) and tetraethylenepentamine (...

Amine-Functionalized MIL-101 Monoliths for CO₂ Removal from Enclosed Environments

The possibility of prolonging space missions—and consequently the permanence of humans in space—depends on the possibility of providing them with an adequate supply of fresh foods to meet their nutritional requirements. This would allow space travelers to mitigate health risks associated with exposure to space radiation, microgravity and psychological stress. In this review, we attempt to critically summarize existing studies with the aim of suggesting possible solutions to overcome the challenges to develop a bio-regenerative life support system (BLSS) that can contribute to life support, supplying food and O2, while removing CO2 on the International Space Station (ISS). We describe the physical constraints and energy requirements for ISS farming in relation to space and energy resources, the problems related to lighting systems and criteria for selecting plants suitable for farming in space and microgravity. Clearly, the dimensions of a growth hardware that can be placed on ISS do not allow to produce enough fresh food to supplement the stored, packaged diet of astronauts; however, experimentation on ISS is pivotal for implementing plant growth systems and paves the way for the next long-duration space missions, including those in cis-lunar space and to the lunar surface.

https://www.mdpi.com/2073-4395/10/5/687/pdf

Challenges for a Sustainable Food Production System on Board of the International Space Station: A Technical Review

A long-term goal for NASA is to enable crewed missions to Mars: first to the vicinity of Mars, and then to the Mars surface. These missions present new challenges for all aspects of spacecraft design in comparison with the International Space Station, as resupply is unavailable in the transit phase, and early return is not possible. Additionally, mass, power, and volume must be minimized for all phases to reduce propulsion needs. Mass reduction is particularly crucial for Mars surface landing and liftoff due to the challenges inherent in these operations for even much smaller payloads. In this paper we describe current and planned developments in the area of carbon dioxide removal to support future crewed Mars missions. Activities are also described that apply to both the resolution of anomalies observed in the ISS CDRA and the design of life support systems for future missions.

/pdf/development-of-carbon-dioxide-removal-systems-for-advanced-47phu9gnw8.pdf

Development of Carbon Dioxide Removal Systems for Advanced Exploration Systems 2012-2013

A vehicle includes console/shifter arrangement includes a vehicle floor, a shifter base member and a console. A shifter base member has oversized fastening apertures arranged to align with threaded apertures in the vehicle floor. Fasteners extending through the oversized fastening apertures engage the threaded apertures and are moveable between an adjusting orientation and a securing orientation. The oversized fastening apertures have a prescribed dimension with respect to the fasteners such that the shifter base member is movable in alignment directions relative to the vehicle floor with the fasteners in the adjusting orientation. The console and the shifter base member are configured to move together as a single unit in the alignment directions while the fasteners are in the adjusting orientation.

Vehicle shift/console arrangement

"NASA's Advanced Exploration Systems (AES) program is pioneering new approaches for rapidly developing prototype systems, demonstrating key capabilities, and validating operational concepts for future human missions beyond Earth orbit" (NASA 2012). These forays beyond the confines of earth's gravity will place unprecedented demands on launch systems. They must not only blast out of earth's gravity well as during the Apollo moon missions, but also launch the supplies needed to sustain a crew over longer periods for exploration missions beyond earth's moon. Thus all spacecraft systems, including those for the separation of metabolic carbon dioxide and water from a crewed vehicle, must be minimized with respect to mass, power, and volume. Emphasis is also placed on system robustness both to minimize replacement parts and ensure crew safety when a quick return to earth is not possible. Current efforts are focused on improving the current state-of-the-art systems utilizing fixed beds of sorbent pellets by seeking more robust pelletized sorbents, evaluating structured sorbents, and examining alternate bed configurations to improve system efficiency and reliability. These development efforts combine testing of sub-scale systems and multi-physics computer simulations to evaluate candidate approaches, select the best performing options, and optimize the configuration of the selected approach, which is then implemented in a full-scale integrated atmosphere revitalization test. This paper describes the carbon dioxide (CO2) removal hardware design and sorbent screening and characterization effort in support of the Atmosphere Resource Recovery and Environmental Monitoring (ARREM) project within the AES program. A companion paper discusses development of atmosphere revitalization models and simulations for this project.

/pdf/development-of-carbon-dioxide-removal-systems-for-advanced-awqytvxndj.pdf

Development of Carbon Dioxide Removal Systems for Advanced Exploration Systems

Development of Carbon Dioxide Removal Systems for Advanced Exploration Systems 2013-2014

A sled system for mounting a parking brake hand lever assembly and a gear shift assembly to a vehicle floor pan, the sled system having a predetermined configuration to mount on a vehicle floor pan.

Sled system for mounting parking brake and shift assemblies

An anti-rattle includes an arrangement configured to couple to a disk brake caliper and a curved spring section that is configured to compress in response to a rattling of the caliper towards the clip, reducing the impact energy of the rattling.

Anti-rattle spring clip

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