Johannes A. Baus
University of Würzburg
34 Papers
313 Citations
Johannes A. Baus is an academic researcher from University of Würzburg. The author has contributed to research in topics: Silylene & Crystal structure. The author has an hindex of 17, co-authored 34 publications.
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Papers
Bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): a silicon(II) compound with both a bidentate and a monodentate amidinato ligand.
TL;DR: Well looked-after: reductive HCl elimination of the λ(6)-silicon(IV) complex 1 leads to theλ(3)- silicon(II) species 2, a novel type of donor-stabilized silylene.
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The Donor‐Stabilized Silylene Bis[N,N′‐diisopropylbenzamidinato(−)]silicon(II): Synthesis, Electronic Structure, and Reactivity
Konstantin Junold,Marco Nutz,Johannes A. Baus,Christian Burschka,Célia Fonseca Guerra,F. Matthias Bickelhaupt,F. Matthias Bickelhaupt,Reinhold Tacke +7 more
TL;DR: A convenient and robust synthesis of bis[N,N'-diisopropylbenzamidinato(-)]silicon(II) (1), a donor-stabilized silylene, has been developed and the four-coordinate species 1' was demonstrated to be the thermodynamically favored isomer in benzene solution.
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Stable Five-Coordinate Silicon(IV) Complexes with SiN4X Skeletons (X=S, Se, Te) and SiX Double Bonds
TL;DR: Silylenes: Reaction of the donor-stabilized silylene 1 with elemental sulfur, selenium, or tellurium led to the formation of 2 a-c [SiN(4)X skeletons], the first stable five-coordinate silicon(IV) compounds with silicon-chalcogen double bonds (see figure).
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Reactivity of the Donor‐Stabilized Silylenes [iPrNC(Ph)NiPr]2Si and [iPrNC(NiPr2)NiPr]2Si: Activation of CO2 and CS2
Felix M. Mück,Johannes A. Baus,Marco Nutz,Christian Burschka,Jordi Poater,F. Matthias Bickelhaupt,F. Matthias Bickelhaupt,Reinhold Tacke +7 more
TL;DR: Activation of CO2 by silylene 1 and the analogous bis(guanidinato)silylene 2 leads to the structurally analogous six-coordinate silicon(IV) complexes 4 and 8, the first silicon compounds with a chelating carbonato ligand.
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Donor‐Stabilized Silylenes with Guanidinato Ligands
TL;DR: The first donor-stabilized silylenes with guanidinato ligands, compounds 4 and 6, were synthesized and structurally characterized in the solid state and in solution.
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