3D printing alias additive manufacturing can transform 3D virtual models created by computer-aided design (CAD) into physical 3D objects in a layer-by-layer manner dispensing with conventional molding or machining. Since the incipiency, significant advancements have been achieved in understanding the process of 3D printing and the relationship of component, structure, property and application of the created objects. Because hydrogels are one of the most feasible classes of ink materials for 3D printing and this field has been rapidly advancing, this Review focuses on hydrogel designs and development of advanced hydrogel-based biomaterial inks and bioinks for 3D printing. It covers 3D printing techniques including laser printing (stereolithography, two-photon polymerization), extrusion printing (3D plotting, direct ink writing), inkjet printing, 3D bioprinting, 4D printing and 4D bioprinting. It provides a comprehensive overview and discussion of the tailorability of material, mechanical, physical, chemical and biological properties of hydrogels to enable advanced hydrogel designs for 3D printing. The range of hydrogel-forming polymers covered encompasses biopolymers, synthetic polymers, polymer blends, nanocomposites, functional polymers, and cell-laden systems. The representative biomedical applications selected demonstrate how hydrogel-based 3D printing is being exploited in tissue engineering, regenerative medicine, cancer research, in vitro disease modeling, high-throughput drug screening, surgical preparation, soft robotics and flexible wearable electronics. Incomparable by thermoplastics, thermosets, ceramics and metals, hydrogel-based 3D printing is playing a pivotal role in the design and creation of advanced functional (bio)systems in a customizable way. An outlook on future directions of hydrogel-based 3D printing is presented.

3D printing of hydrogels: Rational design strategies and emerging biomedical applications

Lithium-sulfur (Li-S) batteries are severely hindered by the low sulfur utilization and short cycling life, especially at high rates. One of the effective solutions to address these problems is to improve the sulfiphilicity of lithium polysulfides (LiPSs) and the lithiophilicity of the lithium anode. However, it is a great challenge to simultaneously optimize both aspects. Herein, by incorporating the merits of strong absorbability and high conductivity of SnS with good catalytic capability of ZnS, a ZnS-SnS heterojunction coated with a polydopamine-derived N-doped carbon shell (denoted as ZnS-SnS@NC) with uniform cubic morphology was obtained and compared with the ZnS-SnS2@NC heterostructure and its single-component counterparts (SnS@NC and SnS2@NC). Theoretical calculations, ex situ XANES, and in situ Raman spectrum were utilized to elucidate rapid anchoring-diffusion-transformation of LiPSs, inhibition of the shuttling effect, and improvement of the sulfur electrochemistry of bimetal ZnS-SnS heterostructure at the molecular level. When applied as a modification layer coated on the separator, the ZnS-SnS@NC-based cell with optimized lithiophilicity and sulfiphilicity enables desirable sulfur electrochemistry, including high reversibility of 1149 mAh g-1 for 300 cycles at 0.2 C, high rate performance of 661 mAh g-1 at 10 C, and long cycle life with a low fading rate of 0.0126% each cycle after 2000 cycles at 4 C. Furthermore, a favorable areal capacity of 8.27 mAh cm-2 is maintained under high sulfur mass loading of 10.3 mg cm-2. This work furnishes a feasible scheme to the rational design of bimetal sulfides heterostructures and boosts the development of other electrochemical applications.

ZnS-SnS@NC Heterostructure as Robust Lithiophilicity and Sulfiphilicity Mediator toward High-Rate and Long-Life Lithium-Sulfur Batteries.

Considerable attention has been devoted to producing antibacterial fabrics due to their very wide applications in medicine, hygiene, hospital, etc. However, the poor antibacterial durability and bad bacterial antiadhesion capacity of most existing antibacterial fabrics limit their applications. In this work, a series of antibacterial and polymeric quaternary ammonium monomers with different alkyl chain length were successfully synthesized to copolymerize with fluorine-containing and other acrylic monomers to generate cationic fluorinated polymer emulsions and durably antibacterial and bacterially antiadhesive cotton fabrics. The relation between antibacterial constituent and its antibacterial activity was investigated. The study indicated that the alkyl chain length and contents of the antibacterial monomers, as well as the add-on percentage of polymer greatly influenced the antibacterial activities of the fabrics. In addition, it was found that incorporation of fluorine component into the polymer greatly...

Durably Antibacterial and Bacterially Antiadhesive Cotton Fabrics Coated by Cationic Fluorinated Polymers

The increasing demand for higher-energy-density batteries driven by advancements in electric vehicles, hybrid electric vehicles, and portable electronic devices necessitates the development of alternative anode materials with a specific capacity beyond that of traditional graphite anodes. Here, the state-of-the-art developments made in the rational design of Si-based electrodes and their progression toward practical application are presented. First, a comprehensive overview of fundamental electrochemistry and selected critical challenges is given, including their large volume expansion, unstable solid electrolyte interface (SEI) growth, low initial Coulombic efficiency, low areal capacity, and safety issues. Second, the principles of potential solutions including nanoarchitectured construction, surface/interface engineering, novel binder and electrolyte design, and designing the whole electrode for stability are discussed in detail. Third, applications for Si-based anodes beyond LIBs are highlighted, specifically noting their promise in configurations of Li-S batteries and all-solid-state batteries. Fourth, the electrochemical reaction process, structural evolution, and degradation mechanisms are systematically investigated by advanced in situ and operando characterizations. Finally, the future trends and perspectives with an emphasis on commercialization of Si-based electrodes are provided. Si-based anode materials will be key in helping keep up with the demands for higher energy density in the coming decades.

Recent Advances in Silicon-Based Electrodes: From Fundamental Research toward Practical Applications

Applications of chitin and chitosan nanofibers in bone regenerative engineering

Permanent antimicrobial cotton fabrics obtained by surface treatment with modified guanidine

The combination of transparency, antimicrobial activities, nonleaching of antimicrobial component and green preparation for poly(vinyl alcohol) (PVA) films is of importance for practical applications in industry. However, until now it remains a challenge. Herein, a facile antimicrobial PVA films containing polyhexamethylene guanidine (PHMG) is reported via a green solution casting method. Such PVA films show high transparency of 91%, above 99.99% of antimicrobial rates against Escherichia coli and Staphylococcus aureus, and nonleaching characteristic of PHMG due to the hydrogen-bond (H-bond) interaction between PHMG and PVA. The thermal stability and mechanical properties of the PVA films are further improved compared to neat PVA film. These antimicrobial films are expected to find promising applications in tissue engineering and packaging fields, which opens up a methodology to prepare nonleaching antimicrobial polymeric materials via H-bond.

Hydrogen-Bond Assembly of Poly(vinyl alcohol) and Polyhexamethylene Guanidine for Nonleaching and Transparent Antimicrobial Films.

Abstract Plastic take-out food containers may release microplastics (MPs) into food and pose a potential risk to food safety and human health. Here, after being subjected to hot water treatment, MPs released from three types of plastic food containers (polypropylene, PP; polyethylene, PE; expanded polystyrene, EPS) were identified by micro-Raman spectroscopy. The results showed that the size of released MPs ranged from 0.8–38 μm and over 96% MPs were smaller than 10 μm. Various MPs concentrations were found from the three types of containers, that is, 1.90 × 104, 1.01 × 105, and 2.82 × 106 particles/L on average from PP, PE, and EPS, respectively. Moreover, based on thermal and morphology analysis, we discovered that both relaxations of the polymer chains in the rubbery state and defects caused by processing techniques might contribute to the release of MPs. Thus, such release can be reduced by increasing the thermal stability of the materials and mitigating the defects generated during production.

Analysis of microplastics released from plastic take-out food containers based on thermal properties and morphology study

A preparation method of an antibacterial guanidine salt copolymer. The antibacterial guanidine salt copolymer is prepared through copolymerization from a hydrophilic antibacterial guanidine salt and a hydrophobic polymer by means of a solution reaction or a melt reaction, reaction molar ratio of the hydrophilic antibacterial guanidine salt to the hydrophobic polymer being 0.5-2. The antibacterial guanidine salt copolymer is amphiphilic and has adjustable terminal groups, so that the copolymer can be directly added to resin having a reactive functional group, and therefore, the antibacterial guanidine salt copolymer is tightly bonded to the basic resin through the reaction between the antibacterial guanidine salt copolymer and the basic resin so that a corresponding product has durable antibacterial function. The copolymer, whether in an aqueous system or a non-aqueous system, can be applied to achieve the antibacterial function, so that usage of the guanidine salt copolymer is greatly broadened.

Preparation method and applications of antibacterial guanidine salt copolymer

Chlorophenols, as a major environmental pollutant, enter water systems through industrial wastewater, agricultural runoff and chemical spills, and they are stable, persistent under natural conditions, and highly hazardous to water resources. The objective of this article is to prepare Ag2S-modified C3N4 three-dimensional network photocatalyst by calcination method to use photocatalysis as an efficient, safe, and environmentally friendly method to degrade chlorophenols. Ag2S/C3N4 has an excellent visible light absorption range, low band gap, effective separation of photogenerated charges, and active free radicals production, all of which make for the enhancement of photocatalytic degradation performance of the Ag2S/C3N4 system. Under the light irradiation (λ ≥ 420 nm), the photocatalytic degradation efficiency of 2,4,6-Trichlorophenol reach 95% within 150 min, and the stable photocatalytic degradation activity can still be maintained under different pH water environment and four degradation cycles. When Ag2S is loaded on ACNs, more photogenerated electrons are generated and subsequent reactions produce highly reactive groups such as •O2− and •OH that will originally be able to continuously attack TCP molecules to degrade pollutants. Therefore, this study shows that the photocatalyst provides a novel research approach for realizing the application in the field of pollutant degradation.

/pdf/multivalent-effect-of-defect-engineered-ag2s-g-c3n4-3d-1qfwovbn.pdf

Multivalent Effect of Defect Engineered Ag2S/g-C3N4 3D Porous Floating Catalyst with Enhanced Contaminant Removal Efficiency

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