Construction of a Bifunctional Pd(0)‐CALB@SiO 2 Hybrid Catalyst for the Synthesis and Arylation of Imidazo[1,2‐a]pyridine in One Pot

In recent years, there has been increasing attention focused on various products belonging to the imidazopyridine family; this class of heterocyclic compounds shows unique chemical structure, versatile optical properties, and diverse biological attributes. The broad family of imidazopyridines encompasses different heterocycles, each with its own specific properties and distinct characteristics, making all of them promising for various application fields. In general, this useful category of aromatic heterocycles holds significant promise across various research domains, spanning from material science to pharmaceuticals. The various cores belonging to the imidazopyridine family exhibit unique properties, such as serving as emitters in imaging, ligands for transition metals, showing reversible electrochemical properties, and demonstrating biological activity. Recently, numerous noteworthy advancements have emerged in different technological fields, including optoelectronic devices, sensors, energy conversion, medical applications, and shining emitters for imaging and microscopy. This review intends to provide a state-of-the-art overview of this framework from 1955 to the present day, unveiling different aspects of various applications. This extensive literature survey may guide chemists and researchers in the quest for novel imidazopyridine compounds with enhanced properties and efficiency in different uses. 

Imidazopyridine Family: Versatile and Promising Heterocyclic Skeletons for Different Applications

The synthesis and chemistry of pyrazoles, imidazoles, 1,2,3-triazoles, 1,2,4-triazoles, and tetrazoles were actively pursued in 2022. No attempt was made to incorporate all the exciting chemistry and biological applications that were published during the year. 

Five-membered ring systems: with more than one N atom

In this report, we developed an efficient one-pot method for the synthesis of 3-phenyl-1-(phenylthio)imidazo[1,5-a]pyridine analogs starting from 2-aminomethylpyridines, benzaldehydes, and sodium benzenesulfinates, which constructed C-N and C-S bonds simultaneously. The method features mild reaction conditions, a wide range of substrates, high atom utilization, and convenient and easily accessible starting materials. 

Iodine-Mediated One-Pot Synthesis of Imidazo[1,5-a]Pyridines

Thioether-Assisted Cu-Catalyzed C5-H Arylation of Imidazo[1,5-a]pyridines.

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Thioether-Assisted Cu-Catalyzed C5-H Arylation of Imidazo[1,5-a]pyridines.