Jian Chen
Central China Normal University
32 Papers
74 Citations
Jian Chen is an academic researcher from Central China Normal University. The author has contributed to research in topics: Computer science & Aryl. The author has an hindex of 8, co-authored 14 publications.
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Papers
Visible-Light-Promoted Transition-Metal-Free Phosphinylation of Heteroaryl Halides in the Presence of Potassium tert-Butoxide.
Jia Yuan,Wai-Pong To,Zi-Yang Zhang,Chang-Duo Yue,Sixuan Meng,Jian Chen,Yungen Liu,Guang-Ao Yu,Chi-Ming Che +8 more
TL;DR: A novel visible-light-promoted C-P bond formation reaction in the absence of both transition metal and photoredox catalysts is disclosed, providing a simple and efficient route to heteroaryl phosphine oxides.
57
Synthesis of peri-Substituted (Naphthalen-1-yl)phosphine Ligands by Rhodium(I)-Catalyzed Phosphine-Directed C-H Arylation.
TL;DR: A novel protocol for effective rhodium(I)-catalyzed C-H arylation of tertiary phosphines has been devised and provides a simple and efficient route to peri-substituted (naphthalen-1-yl)phosphines.
54
Application of a 2-aryl indenylphosphine ligand in the Buchwald-Hartwig cross-coupling reactions of aryl and heteroaryl chlorides under the solvent-free and aqueous conditions.
TL;DR: An efficient solvent-free protocol for the Buchwald-Hartwig cross-coupling reaction of aryl and heteroaryl chlorides with primary and secondary amines using the Pd(dba)2/ligand 1 catalytic system has been developed.
17
2-Aryl-indenylphosphine ligands: design, synthesis and application in Pd-catalyzed Suzuki–Miyaura coupling reactions
Ze-Yu Lian,Jia Yuan,Meng-Qi Yan,Yan Liu,Xue Luo,Qing-Guo Wu,Sheng Hua Liu,Jian Chen,Xiaolei Zhu,Guang-Ao Yu +9 more
TL;DR: A focused library of phosphine ligands was constructed for structural optimization and can be used to perform the Suzuki-Miyaura cross-coupling reaction of aryl and heteroaryl chlorides.
14
An active catalytic system for Suzuki–Miyaura cross-coupling reactions using low levels of palladium loading
TL;DR: An easily available Pd(OAc)2/(2-(anthracen-9-yl)-1H-inden-3-yl) dicyclohexylphosphine/toluene/iPrOH/water catalytic system was developed, which shows high catalytic activity in the Suzuki-Miyaura cross-coupling reactions of a diverse array of aryl and heteroaryl chlorides.
14