Jean-Michel Savéant
Paris Diderot University
517 Papers
9K Citations
Jean-Michel Savéant is an academic researcher from Paris Diderot University. The author has contributed to research in topics: Electron transfer & Cyclic voltammetry. The author has an hindex of 98, co-authored 517 publications. Previous affiliations of Jean-Michel Savéant include University of Paris & École Normale Supérieure.
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Papers
Dimerization of electrochemically generated ion radicals: mechanisms and reactivity factors
TL;DR: In this article, the authors examined the radical-radical character of the coupling of the anion radicals as originally proposed, and pointed out that the original proposals were correct and that the reactivity is governed by the interplay between three factors, bond formation, coulombic repulsion, and solvation.
Effect of Ion Pairing on the Mechanism and Rate of Electron Transfer. Electrochemical Aspects
TL;DR: Ion pairing may have a strong influence on the kinetics and mechanisms of electrochemical reactions as reflected by the location of the corresponding half-wave (or peak) potential as discussed by the authors, which is a strong indicator of the strength of ion pairing.
Theory and practice of enzyme bioaffinity electrodes. Direct electrochemical product detection.
TL;DR: The theoretical analysis is a requisite for a rational and realistic discussion of the analytical performances of the steady-state chronoamperometric and cyclic voltammetric approaches.
Kinetics of electron transfer to organic molecules at solid electrodes in organic media
TL;DR: In this paper, an electrochemical treatment of the former electrodes was proposed, involving the repetitive cycling of the electrode potential within a negative range, and a steady value of the apparent standard rate constant was obtained which was not very different from the values obtained on mercury and on glassy carbon.