Jan Pecak
Vienna University of Technology
15 Papers
12 Citations
Jan Pecak is an academic researcher from Vienna University of Technology. The author has contributed to research in topics: Pincer movement & Chemistry. The author has an hindex of 3, co-authored 7 publications.
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Papers
Synthesis and characterization of bis- and tris-carbonyl Mn(I) and Re(I) PNP pincer complexes
TL;DR: The dissociation of CO was studied by means of DFT calculation revealing in agreement with experimental findings that CO release from [M(κ3P,N,P-PNP)(CO)3]+ is in general endergonic, while for [Mn(κ 3P, n, P-PNPNH-tBu)( CO)3]+, this process is thermodynamically favored.
Synthesis and Catalytic Reactivity of Cobalt Pincer Nitrosyl Hydride Complexes.
TL;DR: In this article, the synthesis, characterization, and catalytic activity of low-spin {CoNO}8 pincer complexes of the type [Co(PCP)(NO)(H)] are described.
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Five-Coordinate Low-Spin {FeNO} 7 PNP Pincer Complexes
Jan Pecak,Berthold Stöger,Matthias Mastalir,Luis F. Veiros,Liliana P. Ferreira,Liliana P. Ferreira,Marc Pignitter,Wolfgang Linert,Karl Kirchner +8 more
TL;DR: Preliminary investigations reveal that [Fe(PNPNH- iPr)(NO)(Cl)]+ efficiently catalyzes the conversion of primary alcohols and aromatic and benzylic amines to yield mono N-alkylated amines in good isolated yields.
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No Transition Metals Required - Oxygen Promoted Synthesis of Imines from Primary Alcohols and Amines under Ambient Conditions.
Daniel Himmelbauer,Radu A. Talmazan,Stefan Weber,Jan Pecak,Antonio Thun-Hohenstein,Maxine-Sophie Geissler,Lucas Pachmann,Marc Pignitter,Maren Podewitz,Karl Kirchner +9 more
TL;DR: In this paper , the synthesis of imines from benzyl alcohols and anilines, promoted by KOtBu under aerobic conditions at room temperature in the absence of any transition-metal catalyst is presented.
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Visible light-induced cis/trans isomerization of dicarbonyl Fe(II) PNP pincer complexes
Jan Pecak,Mathias Glatz,Berthold Stöger,Roland W. Bittner,Helmuth Hoffmann,Andrew J. Atkins,Leticia González,Karl Kirchner +7 more
TL;DR: In this article, the synthesis and characterization of dicarbonyl Fe(II) PNP pincer complexes of the type cis-[Fe(PNP-iPr)(CO)2(X)]+ (X = Br, Cl) is described.
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