Recent development in peptide coupling reagents

New trends in peptide coupling reagents

2‐chloro‐4,6‐disubstituted‐1,3,5‐triazines. a novel group of condensing reagents

The synthesis, properties, and application of condensing reagents derived from 1,3,5-triazines are described. The mechanism of activation of carboxylic function, structure of reactive intermediates, and mechanism of acylation of nucleophiles are presented. The synthetic versatility of mono- and bifunctional reagents for syntheses in solution, triazine-based immobilized reagents, chiral triazines for enantiodifferentiating syntheses, are discussed. The scope and limitation of the synthetic utility of triazine reagents in the preparation of heterocyclic compounds, amides, esters, oligopeptides-including large-scale syntheses and use in the combinatorial chemistry-is demonstrated.

Triazine-based condensing reagents

New Optoelectronic Materials Based on Bitriazines: Synthesis and Properties

Cyanuric Chloride Derivatives. III. Alkoxy-s-triazines

Cyanuric Chloride Derivatives. VII. Transesterification Reactions of Alkoxy-s-triazines. Polyammelide Ethers

Cyanuric Chloride Derivatives. VIII. Vinylamino-s-triazines

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Papers

Cyanuric Chloride Derivatives. III. Alkoxy-s-triazines

Cyanuric Chloride Derivatives. VII. Transesterification Reactions of Alkoxy-s-triazines. Polyammelide Ethers

Cyanuric Chloride Derivatives. VIII. Vinylamino-s-triazines