The original photoelectric effect was discovered by Hertz(1) in 1887 while he was investigating the properties of electromagnetic waves. It was observed that a spark would jump a gap between two electrodes more readily when the electrodes were illuminated with light, ultraviolet light having a greater effectiveness than light from the visible region of the spectrum. This simple observation, however, was to have profound impact on our conception of how radiation and matter interact.

Photoemission Phenomena at Metallic and Semiconducting Electrodes

Photoelectrochemical water splitting has been frontier research in the last 50 years to meet the energy demand from sustainable hydrogen production. Various materials have designed and engineered to split the water to the constituents. However, the efforts in this regard do not lead the process to a viable scale. The chapter deals with the perspective on the current scenario of material designing approach and its consequences. Also, a revisit to the genesis of the photoelectrochemical water splitting in the boom years and cited the essential articles in the field appeared before 1990 in the form of a chronological table. A prospect for the future of the field has been suggested based on the effect of the photon as well as electric field together in the system—also, a proposition on the materials design aspects given.

Hydrogen from photo-electrocatalytic water splitting

Effective threshold energy of photoelectrochemical process on semiconductor electrodes

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Effective threshold energy of photoelectrochemical process on semiconductor electrodes