Chelation-Assisted Catalytic C-C, C-Si, and C-Halogen Bond Formation by Substitution via the Cleavage of C(sp2)-H and C(sp3)-H Bonds

An Electrochemical γ-C-H Arylation of Amines in Continuous Flow

This review presents a selection of recent advances in C–H activation chemistry along with comparisons of earlier examples in order to track progress in a particular area. Wherever possible, the role, or perceived role, of the metal is presented. Whenever a particular distinction is possible, both inter- and intra-molecular functionalizations of the C–H bond of sp3-, sp2-, and sp-hybridized carbon atoms are covered. The chapter emphasizes synthetic applications, which have been particularly remarkable, as C–H functionalizations are now employed as key steps in the synthesis of bioactive molecules.

10.03 – Synthetic Reactions via C–H Bond Activation: C–C and C–E Bond Formation

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10.03 – Synthetic Reactions via C–H Bond Activation: C–C and C–E Bond Formation