Atmospheric pressure plasmas: A review

Biomass gasification presents highly interesting possibilities for expanding the utilization of biomass as power generation using internal combustion engines or turbines. However, the need to reduce the tar in the producer gas is very important. The successful application of producer gas depends not only on the quantity of tar, but also on its properties and compositions, which is associated with the dew-point of tar components. Class 5, 4, and 2 tar become a major cause of condensation which can foul the engines and turbines. Hence, the selectivity of tar treatment method to remove or convert class 5, 4, and 2 tar is a challenge in producer gas utilization. This review was conducted to present the recent studies in tar treatment from biomass gasification. The new technologies with their strengths and the weaknesses in term of tar reduction are discussed.

Tar reduction in biomass producer gas via mechanical, catalytic and thermal methods: A review

In this work, comprehensive investigation was done on the oxygen partial pressure-dependent behavior of the various catalysts using a flow-type plasma-driven catalyst (PDC) reactor. These data provide a useful guideline for the optimization of the cycled system using adsorption and the O 2 plasma-driven catalysis of adsorbed volatile organic compounds (VOCs). The potentials of the tested catalysts for the cycled system were evaluated based on the enhancement factor and the adsorption capability. All the tested materials (TiO 2 , γ-Al 2 O 3 , zeolites) exhibited positive enhancement factor, while negative values with the dielectric-barrier discharge (DBD) plasma alone. TiO 2 catalysts showed the highest enhancement factor of about 100 regardless of the type of metal catalysts and their supporting amount. Based on the experimental findings in this study and the literature information, a plausible mechanism of plasma-driven catalysis of VOCs was suggested.

Oxygen partial pressure-dependent behavior of various catalysts for the total oxidation of VOCs using cycled system of adsorption and oxygen plasma

Microwave plasmas sustained at atmospheric pressure, for instance by electromagnetic surface waves, can be efficiently used to abate greenhouse-effect gases such as perfluorinated compounds. As a working example, we study the destruction and removal efficiency (DRE) of SF6 at concentrations ranging from 0.1% to 2.4% of the total gas flow where N2, utilized as a purge gas, is the carrier gas. O2 is added to the mixture at a fixed ratio of 1.2–1.5 times the concentration of SF6 to ensure full oxidation of the SF6 fragments, providing thereby scrubbable by-products. Fourier-transform infrared spectroscopy has been utilized for identification of the by-products and quantification of the residual concentration of SF6. Optical emission spectroscopy was employed to determine the gas temperature of the nitrogen plasma. In terms of operating parameters, the DRE is found to increase with increasing microwave power and decrease with increasing gas flow rate and discharge tube radius. Increasing the microwave power, in the case of a surface-wave discharge, or decreasing the gas flow rate increases the residence time of the molecules to be processed, hence, the observed DRE increase. In contrast, increasing the tube radius or the gas-flow rate increases the degree of radial contraction of the discharge and, therefore, the plasma-free space close to the tube wall: this comparatively colder region favors the reformation of the fragmented SF6 molecules, and enlarging it lowers the destruction rate. DRE values higher than 95% have been achieved at a microwave power of 6 kW with 2.4% SF6 in N2 flow rates up to 30 standard l/min.

Abatement of perfluorinated compounds using microwave plasmas at atmospheric pressure

Generation of microdischarges inside porous ceramics by AC high voltage was explored. The physical properties of the microdischarges were investigated by electrical measurements, photographic visualization, and optical emission spectroscopy. The effects of pore size, discharge power, and gas mixture composition on the discharge properties and its development are described. The optimum generation and distribution of the microdischarges was observed with pore sizes of 50 and 80 μm. The emission spectra of the microdischarges indicated their strongly non-equilibrium character. A theoretical analysis of the microdischarge mechanism is provided, accounting for the pore size and the elementary processes such as ionization, recombination, and ambipolar diffusion.

Electrical and Optical Properties of AC Microdischarges in Porous Ceramics

A 3.0 GHz pulsed microwave source operated at atmospheric pressure with a pulse power of 1.4 MW, a maximum repetition rate of 40 Hz, and a pulse length of 3.5 µs is experimentally studied with respect to the ability to remove NOx from synthetic exhaust gases. Experiments in gas mixtures containing N2/O2/NO with typically 500 ppm NO are carried out. The discharge is embedded in a high-Q microwave resonator, which provides a reliable plasma ignition. Vortex flow is applied to the exhaust gas to improve gas treatment. Concentration measurements by Fourier transform infrared spectroscopy confirm an NOx reduction of more than 90% in the case of N2/NO mixtures. The admixture of oxygen lowers the reductive potential of the reactor, but NOx reduction can still be observed up to 9% O2 concentration. Coherent anti-Stokes Raman scattering technique is applied to measure the vibrational and rotational temperature of N2. Gas temperatures of about 400 K are found, whilst the vibrational temperature is 3000-3500 K in pure N2. The vibrational temperature drops to 1500 K when O2 and/or NO are present. The randomly distributed relative frequency of occurrence of selected breakdown field intensities is measured by a calibrated, short linear-antenna. The breakdown field strength in pure N2 amounts to 2.2×106 V m-1, a value that is reproducible within 2%. In the case of O2 and/or NO admixture, the frequency distribution of the breakdown field strength scatters more and extends over a range from 3 to 8×106 V m-1.

http://iopscience.iop.org/article/10.1088/0963-0252/11/1/301/pdf

Pulsed microwave discharge at atmospheric pressure for NOx decomposition

Pulsed microwave discharges operated at atmospheric pressure in gas mixtures containing N2, O2, and NO are investigated experimentally and theoretically for various gas mixture constituents and operating conditions with respect to the ability of exhaust gas purification. The rotational gas temperature and the vibrational temperature of N2 are derived from CARS measurements. The composition of the exhaust gas after treatment is monitored using FTIR spectroscopy. The processes of the chemical, electronic, and vibrational kinetics are described by a model that has been developed to calculate the species densities. The results obtained show that in N2/NO gas mixtures an overall reduction of NOx takes place. In the case of N2/O2/NO gas mixtures, no net reduction of NOx is achieved for a pulsed microwave power below 3600 W, a pulse length of 50 μs, and a typical repetition frequency of 2 kHz.

Studies on Gas Purification by a Pulsed Microwave Discharge at 2.46 GHz in Mixtures of N2/NO/O2 at Atmospheric Pressure

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Pulsed microwave discharge at atmospheric pressure for NOx decomposition

Studies on Gas Purification by a Pulsed Microwave Discharge at 2.46 GHz in Mixtures of N2/NO/O2 at Atmospheric Pressure