Ilja Rodstein
Ruhr University Bochum
15 Papers
11 Citations
Ilja Rodstein is an academic researcher from Ruhr University Bochum. The author has contributed to research in topics: Ylide & Chemistry. The author has an hindex of 8, co-authored 12 publications.
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Papers
A Highly Active Ylide-Functionalized Phosphine for Palladium-Catalyzed Aminations of Aryl Chlorides
Philip Weber,Thorsten Scherpf,Ilja Rodstein,Dominik Lichte,Lennart T. Scharf,Lukas J. Gooßen,Viktoria H. Gessner +6 more
TL;DR: Benchmark studies showed that YPhos-Pd complexes are superior to the best-known phosphine ligands in room-temperature aminations of aryl chlorides.
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Ylide-Functionalized Phosphine (YPhos)–Palladium Catalysts: Selective Monoarylation of Alkyl Ketones with Aryl Chlorides
Xiao-Qiang Hu,Dominik Lichte,Ilja Rodstein,Philip Weber,Ann-Katrin Seitz,Thorsten Scherpf,Viktoria H. Gessner,Lukas J. Gooßen +7 more
TL;DR: Ylide-functionalized phosphine (YPhos) ligands allow the palladium-catalyzed α-arylation of alkyl ketones with aryl chlorides with record setting activity and the succinct synthesis of ε-caprolactone derivatives.
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Palladium Complexes based on Ylide‐Functionalized Phosphines (YPhos): Broadly Applicable High‐Performance Precatalysts for the Amination of Aryl Halides at Room Temperature
Jens Tappen,Ilja Rodstein,Katie McGuire,Angela Großjohann,Julian Löffler,Thorsten Scherpf,Viktoria H. Gessner +6 more
TL;DR: Palladium allyl, cinnamyl, and indenyl complexes with the ylide‐substituted phosphines revealed to be universal precatalysts for various amines and aryl halides making L2 to one of the most efficient ligands in C−N coupling reactions.
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Coupling of Reformatsky Reagents with Aryl Chlorides Enabled by Ylide-Functionalized Phosphine Ligands
Zhiyong Hu,Xiao-Jing Wei,Jens Handelmann,Ann-Katrin Seitz,Ilja Rodstein,Viktoria H. Gessner,Lukas J. Gooßen +6 more
TL;DR: In this paper, a cyclohexyl-YPhos ligand bearing an ortho-tolyl-substituent in the backbone was used for the use of aryl chlorides in room temperature couplings of reformatsky reagents.
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Efficient Pd-Catalyzed Direct Coupling of Aryl Chlorides with Alkyllithium Reagents.
Thorsten Scherpf,Henning Steinert,Angela Großjohann,Katharina Dilchert,Jens Tappen,Ilja Rodstein,Viktoria H. Gessner +6 more
TL;DR: Palladium catalysts based on ylide‐substituted phosphines (YPhos) were found to be excellently suited for this transformation giving high selectivities at room temperature with a variety of aryl chlorides without the need for an additional transmetallation reagent.
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