Plesovice zircon : A new natural reference material for U-Pb and Hf isotopic microanalysis

We present the first finding of continental crust-derived Precambrian zircons in garnet/spinel pyroxenite veins within mantle xenoliths carried by the Neogene Hannuoba basalt in the central zone of the North China Craton (NCC). Petrological and geochemical features indicate that these mantle-derived composite xenoliths were formed by silicic melt^lherzolite interaction. The Precambrian zircon ages can be classified into three age groups of 2·4^2·5 Ga, 1·6^2·2 Ga and 0·6^1·2 Ga, coinciding with major geological events in the NCC. These Precambrian zircons fall in the field of continental granitoid rocks in plots of U/Yb vs Hf and Y. Their igneous-type REE patterns and metamorphic zircon type CL images indicate that they were not crystallized during melt^peridotite interaction and subsequent high-pressure metamorphism.The 2·5 Ga zircons have positive eHf(t) values (2·9^10·6), whereas the younger Precambrian zircons are dominated by negative eHf(t) values, indicating an ancient continental crustal origin.These observations suggest that the Precambrian zircons were xenocrysts that survived melting of recycled continental crustal rocks and were then injected with silicate melt into the host peridotite. In addition to the Precambrian zircons, igneous zircons of 315 3 Ma (2 ), 80^170 Ma and 48^64 Ma were separated from the garnet/spinel pyroxenite veins; these provide evidence for lower continental crust and oceanic crust recycling-induced multi-episodic melt^peridotite interactions in the central zone of the NCC. The combination of the positive eHf(t) values (2·91^24·6) of the 315 Ma zircons with the rare occurrence of 302^324 Ma subduction-related diorite^granite plutons in the northern margin of the NCC implies that the 315 Ma igneous zircons might record melt^peridotite interactions in the lithospheric mantle induced by Palaeo-Asian oceanic crust subduction. Igneous zircons of age 80^170 Ma generally coexist with the Precambrian metamorphic zircons and have lower Ce/Yb and Th/U ratios, higher U/Yb ratios and greater negative Eu anomalies.The eHf(t) values of these zircons vary greatly from ^47·6 to 24·6.The 170^110 Ma zircons are generally characterized by negative eHf(t) values, whereas the 110^100 Ma zircons have positive eHf(t) values.These observations suggest that melt^peridotite interactions at 80^170 Ma were induced by partial melting of recycled continental crust. The 48^64 Ma igneous zircons are characterized by negligible Ce anomalies, unusually high REE, U and Th contents, and positive eHf(t) values.These features imply that the melt^peridotite interactions at 48^64 Ma could be associated with a depleted mantle-derived carbonate melt or fluid.

Continental and Oceanic Crust Recycling-induced Melt^Peridotite Interactions in the Trans-North China Orogen: U^Pb Dating, Hf Isotopes and Trace Elements in Zircons from Mantle Xenoliths

Principles of isotope geology: 2nd edition, by Gunter Faure. John Wiley & Sons, Inc., 1986, 589p., $42.95 (ISBN 0-471-86412-9)

Hf isotopic compositions of the standard zircons and baddeleyites used in U-Pb geochronology

The research on electrochemical double layer capacitors (EDLC), also known as supercapacitors or ultracapacitors, is quickly expanding because their power delivery performance fills the gap between dielectric capacitors and traditional batteries. However, many fundamental questions, such as the relations between the pore size of carbon electrodes, ion size of the electrolyte, and the capacitance have not yet been fully answered. We show that the pore size leading to the maximum double-layer capacitance of a TiC-derived carbon electrode in a solvent-free ethyl-methylimmidazolium-bis(trifluoro-methane-sulfonyl)imide (EMI-TFSI) ionic liquid is roughly equal to the ion size (∼0.7 nm). The capacitance values of TiC−CDC produced at 500 °C are more than 160 F/g and 85 F/cm3 at 60 °C, while standard activated carbons with larger pores and a broader pore size distribution present capacitance values lower than 100 F/g and 50 F/cm3 in ionic liquids. A significant drop in capacitance has been observed in pores that w...

Relation between the ion size and pore size for an electric double-layer capacitor.

Lunar meteorites provide a wider sampling of the lunar surface compared to the samples collected during the Apollo and Luna Missions. Apatite is the main hydroxyl-bearing (proxy for water) mineral in lunar samples, especially in basaltic rocks. Apatite is also amenable to in-situ U-Pb age dating studies. The ages of lunar basaltic meteorites also span over a larger range compared to basaltic samples from Apollo and Luna collections. Thus, by determining the age, the H-content, and the H isotopic composition of apatites from lunar basaltic meteorites, it is possible to investigate any secular variation in the water contents of the lunar interior.

Tracking secular changes in the "water" content of lunar interior using basaltic lunar meteorites

The Hydrogen Isotopic Composition of Apatites in Lunar Impact-Melt Breccias

We describe results from a new technique using dual beam FIB/SEM with which impact residues can be extracted from microcraters and analysed by EDS This will allow the determination of residue compositions from Stardust craters

/pdf/extraction-and-analysis-of-microcrater-residues-using-hic99wdyrs.pdf

Extraction and analysis of microcrater residues using focused ion beam microscopy

Compositional groups are defined in residue from Stardust craters (1-9 Dc) by qualitative EDS. These compositional groups are being further studied by a FIB-SEM technique to determine representative residue compositions.

Stardust microcrater residue compositional groups

Investigating the H2O content and H isotopic composition of the primitive lunar magma ocean (LMO) cumulates

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