Geopolymer, green alkali activated cementitious material: Synthesis, applications and challenges

Incorporation of nano-materials in cement composite and geopolymer based paste and mortar – A review

Fresh, mechanical and microstructural properties of alkali-activated composites incorporating nanomaterials: A comprehensive review

Characterization and properties of geopolymer nanocomposites with different contents of nano-CaCO3

Geopolymers are novel cementitious materials that have the potential to replace conventional Portland cement composites completely. The production of geopolymer composites has a lower carbon footprint and uses less energy than the production of Portland cement. Recently efforts have been made to incorporate different types of nanoparticles (NPs) in geopolymer composites to enhance the properties of the composite with improved performances. Nanotechnology is one of the most active research areas with novel science and valuable applications that have gradually gained attention, especially during the last two decades. Many studies have been undertaken to date in order to understand better the impacts of NPs addition on the fresh, physical, mechanical, durability, and microstructure properties of geopolymer composites. In the current comprehensive review paper, the effects of different NP types on the most essential fresh, mechanical, durability, and microstructure characteristics of geopolymer paste, mortar, and concrete composites were reviewed, analyzed, and discussed in detail. In this regard, more than 280 published papers were used to create an extensive database that includes the main features of geopolymer composites modified with different NPs. In addition, the main mechanisms behind the influence of different NP types on the properties of geopolymer composites were examined. Past progress, recent drifts, current obstacles, and the benefits and drawbacks of these geopolymer composites enhanced with NPs were also highlighted. Based on the findings of this study, the addition of NPs has a promising future for developing high-performance geopolymer composites that the construction industry can efficiently implement due to significant improvements in strength, durability, microstructure by providing additional C–S–H, N-A-S-H, and C-A-S-H gels as well as filling nano-pores in the geopolymer matrix. 

The role of nanomaterials in geopolymer concrete composites: A state-of-the-art review

Abstract—This paper presents the effects of mixing procedures on mechanical properties of flyash-based geopolymer matrices containing nanosilica (NS) at 0.5%, 1.0%, 2.0%, and 3.0% by weight. Comparison is made with conventional mechanical dry-mixing of NS with flyash and wet-mixing of NS in alkaline solutions. Physical and mechanical properties are investigated using X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM). Results show that generally the addition of NS particles enhanced the microstructure and improved flexural and compressive strengths of geopolymer nanocomposites. However, samples, prepared using dry-mixing approach, demonstrate better physical and mechanical properties comparing to wet-mixing samples.

Characteristics of Nanosilica-Geopolymer Nanocomposites and Mixing Effect

Geopolymer composites reinforced with flax fabrics and nanoclay are fabricated and studied for physical and mechanical properties using X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscope (SEM). Nanoclay platelets at a weight of 1.0%, 2.0%, and 3.0% were added to geopolymer pastes. Nanoclay at 2.0 wt.% was found to improve density and decrease porosity while improving flexural strength and post-peak toughness. A microstructural analysis indicated that nanoclay behaves as filler and as an activator supporting geopolymeric reaction while producing a higher content geopolymer gel improving the microstructure of binders. The process enhances adhesion between the geopolymer matrix and flax fibres. Keywords—Flax fibres, geopolymer, mechanical properties, nanoclay.

Utilization of Nanoclay to Reinforce Flax Fabric-Geopolymer Composites

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Characteristics of Nanosilica-Geopolymer Nanocomposites and Mixing Effect

Utilization of Nanoclay to Reinforce Flax Fabric-Geopolymer Composites