The principal toughening mechanism of a substantially toughened, rubber-modified epoxy has again been shown to involve internal cavitation of the rubber particles and the subsequent formation of shear bands. Additional evidence supporting this sequence of events which provides a significant amount of toughness enhancement, is presented. However, in addition to this well-known mechanism, more subtle toughening mechanisms have been found in this work. Evidence for such mechanisms as crack deflection and particle bridging is shown under certain circumstances in rubber-modified epoxies. The occurrence of these toughening mechanisms appears to have a particle size dependence. Relatively large particles provide only a modest increase in fracture toughness by a particle bridging/crack deflection mechanism. In contrast, smaller particles provide a significant increase in toughness by cavitation-induced shear banding. A critical, minimum diameter for particles which act as bridging particles exists and this critical diameter appears to scale with the properties of the neat epoxy. Bimodal mixtures of epoxies containing small and large particles are also examined and no synergistic effects are observed.

/pdf/influence-of-particle-size-and-particle-size-distribution-on-2othozgvms.pdf

Influence of particle size and particle size distribution on toughening mechanisms in rubber-modified epoxies

Polyactide (PLA) was blended with an ethylene/n-butyl acrylate/glycidyl methacrylate (EBA-GMA) terpolymer and a zinc ionomer of ethylene/methacrylic acid (EMAA-Zn) copolymer. The phase morphology of the resulting ternary blends and its relationship with impact behaviors were studied systematically. Dynamic vulcanization of EBA-GMA in the presence of EMAA-Zn was investigated by torque rheology, and its cross-link level was evaluated by dynamic mechanical analysis. Reactive compatibilization between PLA and EBA-GMA was studied using Fourier transform infrared spectroscopy. The dispersed domains in the ternary blends displayed a “salami”-like phase structure, in which the EMAA-Zn phase evolved from occluded subinclusions into continuous phase with decrease in the EBA-GMA/EMAA-Zn ratio. An optimum range of particle sizes of the dispersed domains for high impact toughness was identified. Also, the micromechanical deformation process of these ternary blends was also investigated by observation of the impact-fra...

Interaction of Microstructure and Interfacial Adhesion on Impact Performance of Polylactide (PLA) Ternary Blends

The influence of block copolymer microstructure on the toughness of compatibilized polylactide/polyethylene blends

Failure mechanisms in polyolefines: The role of crazing, shear yielding and the entanglement network

This report is a review of the factors that influence the impact resistance of high polymers, with an emphasis on crystalline polymers. The phenomenology of polymeric fracture is examined, including brittle and ductile failure, and the ductile-brittle transition temperature (DBTT). An in-depth discussion of the effects of crystalline morphology follows, with special attention given to the influence of spherulite size, fillers, processing conditions, transitions/relaxations, and multilayer coextrusion. Next, rubber phase addition is considered, including mechanisms, morphology, rubber type and particle size, and test conditions. Finally, common impact test methods are surveyed, including pendulum, falling weight, tensile impact, and tensile elongation tests.

Polymer toughness and impact resistance

https://ris.utwente.nl/ws/files/6436071/Borggreve89impact.pdf

Impact behaviour of nylon-rubber blends: 6. Influence of structure on voiding processes; toughening mechanism

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Impact behaviour of nylon-rubber blends: 6. Influence of structure on voiding processes; toughening mechanism