H.A. Budding
15 Papers
272 Citations
H.A. Budding is an academic researcher. The author has contributed to research in topics: Organometallic chemistry & Nucleophile. The author has an hindex of 10, co-authored 15 publications.
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Papers
Studies in group IV organometallic chemistry : XXIV. Structure of products obtained in the hydrostannation of ethynes
TL;DR: In this paper, the identity of the resulting products was established by means of elementary analysis, infrared absorption spectroscopy and proton magnetic resonance spectrographs (MAGS) using a variety of mono-and disubstituted ethynes.
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Studies in group IV organometallic chemistry XXVII. Isomerization of the primary trans-addition products formed in the hydrostannation of ethynes
TL;DR: In this article, it was shown that the isomerization of the primary trans-addition products formed in the hydrostannation of ethynes has been shown to proceed under the influence of organotin radicals.
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Studies in group VI organometallic chemistry XXV. Necleophilic trans-addtition of organotin hydrides to carbon — carbon triple bonds
TL;DR: In the case of diethyl ethynedicarboxylate, the nucleophilic attack of the hydride hydrogen on carbon is the first and rate-determining step.
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Studies in group IV organometallic chemistry XXVI. Free radical trans-addition of organotin hydrides to carbon-carbon triple bonds
A.J. Leusink,H.A. Budding +1 more
TL;DR: In this paper, it was shown that hydrostannation of unsaturated bonds can proceed by an ionic as well irS by a free radical chain mechanism, lending to cc-adducts in the case of monosubstituted electrophilicethynes.
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Studies in group iv organometallic chemistry. XX: Addition of Trialkyltin Hydrides to Substituted Acetylenes: The Structure of the Addition Products†
TL;DR: In this article, the identity and geometry of the resulting 1:1 adducts have been established by means of GLC, IR and NMR spectroscopy, elementary analysis and degradation reactions.
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