Guilherme Volpe Bossa
Sao Paulo State University
42 Papers
85 Citations
Guilherme Volpe Bossa is an academic researcher from Sao Paulo State University. The author has contributed to research in topics: Charge density & Differential capacitance. The author has an hindex of 12, co-authored 37 publications. Previous affiliations of Guilherme Volpe Bossa include North Dakota State University.
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Papers
Emergence of a Stern Layer from the Incorporation of Hydration Interactions into the Gouy-Chapman Model of the Electrical Double Layer.
TL;DR: The mean-field model, which is physically consistent and conceptually similar to the classical Gouy-Chapman model, allows the incorporation of ion specificity, accounts for hydration properties of charged surfaces, and predicts Stern layer properties, which are analyzed in terms of the effective size of the hydrated counterions.
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Incorporation of ion and solvent structure into mean-field modeling of the electric double layer.
TL;DR: How various theoretical models predict structural properties of the electric double layer such as the differential capacitance and compare some of these predictions with computer simulations are discussed.
81
Investigations of the influence of liposome composition on vesicle stability and drug transfer in human plasma: a transfer study
Stephan Holzschuh,Kathrin Kaeß,Guilherme Volpe Bossa,Christiane Decker,Alfred Fahr,Sylvio May +5 more
TL;DR: The results suggest that mTHPC fits best into fluid, unmodified bilayers when the drug-to-lipid ratio is low and that the drug to be associated with the host membrane in two distinct states of which only one interacts directly with the plasma compartment.
27
Differential capacitance of ionic liquids according to lattice-gas mean-field model with nearest-neighbor interactions.
TL;DR: The Bragg-Williams free energy is used to incorporate nearest-neighbor interactions into the lattice gas model of a solvent-free ionic liquid near a planar electrode and the differential capacitance is calculated from solutions of the mean-field consistency relation, arriving at an explicit expression in the limit of a weakly charged electrode.
Modeling the Camel-To-Bell Shape Transition of the Differential Capacitance Using Mean-Field Theory and Monte Carlo Simulations
Guilherme Volpe Bossa,Guilherme Volpe Bossa,Daniel L. Z. Caetano,Sidney J. de Carvalho,Klemen Bohinc,Sylvio May +5 more
TL;DR: Mean-field electrostatics is used to calculate the differential capacitance of an electric double layer formed at a planar electrode in a symmetric 1:1 electrolyte and it is shown that, if a Stern layer is introduced, its thickness dependence on the ion size is non-monotonic or, depending on the salt concentration, even inversely proportional.
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