Gregory M. Ferrence
Purdue University
6 Papers
176 Citations
Gregory M. Ferrence is an academic researcher from Purdue University. The author has contributed to research in topics: Isocyanide & Nickel. The author has an hindex of 5, co-authored 6 publications.
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Papers
Self-assembled monolayers of dithiols, diisocyanides, and isocyanothiols on gold: ‘chemically sticky’ surfaces for covalent attachment of metal clusters and studies of interfacial electron transfer
TL;DR: The self-assembled monolayers (SAMs) of the double-ended dithiols 4,4−biphenyldithiol, and αα-p -xylidithiol were characterized using reflection-absorption infrared spectroscopy (RAIR), optical ellipsometry, and advancing contact-angle ( θ a ) measurements as discussed by the authors.
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A Class of Halide-Supported Trinuclear Nickel Clusters [Ni3(μ3-L)(μ3-X)(μ2-dppm)3]n+ (L = I-, Br-, CO, CNR; X = I-, Br-; n = 0, 1; dppm = Ph2PCH2PPh2): Novel Physical Properties and the Fermi Resonance of Symmetric μ3-η1 Bound Isocyanide Ligands
David A. Morgenstern,Gregory M. Ferrence,John Washington,Jason I. Henderson,Laurence Rosenhein,Jerald D. Heise,Phillip E. Fanwick,Clifford P. Kubiak +7 more
TL;DR: The dihalide capped trinuclear nickel clusters Ni3(μ3-X)2(μ2-dppm)3 (X = I (1a), Br (1b); dppm = Ph2PCH2PPh2) were synthesized and converted to their respective monocations as mentioned in this paper.
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Covalent Attachment of Nickel Clusters to Gold Electrode Surfaces. Formation of Rectifying Molecular Layers
Gregory M. Ferrence,Jason I. Henderson,Dirk G. Kurth,David A. Morgenstern,and Thomas Bein,Clifford P. Kubiak +5 more
TL;DR: In this paper, the disulfide linked "dimer of trimers" cluster [{Ni3(μ3-I)(μ2-dppm)3 (μ3,η1-C⋮NC6H4S-)} was prepared by reaction of 2 equiv of 4,4-bis(isocyano)diphenyl disulfides, 4.
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Infrared spectroelectrochemical and electrochemical kinetics studies of the reaction of nickel cluster radicals [Ni3(μ2-dppm)3(μ3-L) (μ3I)]•(L = CNR, R = CH3, i-C3H7, C6H11, CH2C6H5, t-C4H9, 2,6-Me2C6H3; L = CO) with carbon dioxide
TL;DR: In this paper, a mechanism for catalytic reduction of CO 2 involving CO 2 activation on the isocyanide-capped face of the trinuclear nickel clusters is proposed.
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High-pressure synthesis of [Ru2(μ-dppm)2 (μ-CO)(CO4, Ru2(μ-dppm)(μ-dmpm) (μ-CO)(CO4], and [Ru(dcypm)(CO)3] from Ru3(CO)12 and the diphosphines: R2PCH2PR2; R = CH3(dmpm), C6H5(dppm) and C6H11 (dcypm). Crystal and molecular structures of [Ru2(μ-dppm)2(μ-CO)(CO)4], and [Ru(dcypm)(CO)3]
TL;DR: In this article, the high pressure (1300 psi CO, 120°C) reactions of Ru3(CO)12 with the diphosphines R2PCH2PR2; R = CH3 (dmpm), C6H5 (dppm), and C 6H11 (dcypm) are reported.
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