Gernot Frenking
Nanjing Tech University
798 Papers
7.7K Citations
Gernot Frenking is an academic researcher from Nanjing Tech University. The author has contributed to research in topics: Chemistry & Molecule. The author has an hindex of 93, co-authored 766 publications. Previous affiliations of Gernot Frenking include Donostia International Physics Center & ETH Zurich.
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Papers
Ruthenium(II) complexes of N-heterocyclic carbenes derived from imidazolium-linked cyclophanes.
TL;DR: The results reveal that ruthenium(ii)-[(η(1)-NHC)2:(η (6)-arene)] is more covalently than electrostatically bonded and that the degree of covalence is larger in PHCs than in NHCs or Enders' carbenes.
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Quadruple bonding of bare group-13 atoms in transition metal complexes.
TL;DR: Density functional theory calculations at the M06-D3/def2-TZVPPD level of the group-13 anion complexes EFe(CO)3- (E = B-Tl) and the isoelectronic neutral and charged boron adducts BTM( CO)3q give tetrahedral geometries in the 1A1 electronic ground state as equilibrium structures.
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Active versus Passive Substituent Participation in the Auxiliary‐Mediated Asymmetric Synthesis of an Octahedral Metal Complex
Liang-An Chen,Jiajia Ma,Mehmet Ali Celik,Hong‐Lang Yu,Zexing Cao,Gernot Frenking,Lei Gong,Eric Meggers,Eric Meggers +8 more
TL;DR: A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal-centered configuration Λ or Δ depending only on the chemical composition of the side chain of aChiral salicyloxazoline auxiliary.
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