Gernot Frenking
Nanjing Tech University
798 Papers
7.7K Citations
Gernot Frenking is an academic researcher from Nanjing Tech University. The author has contributed to research in topics: Chemistry & Molecule. The author has an hindex of 93, co-authored 766 publications. Previous affiliations of Gernot Frenking include Donostia International Physics Center & ETH Zurich.
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Papers
Di-ortho-beryllated Carbodiphosphorane: A Compound with a Metal–Carbon Double Bond to an Element of the s-Block
Magnus R. Buchner,Sudip Pan,Christina Poggel,Nils Spang,Matthias Müller,Gernot Frenking,Jörg Sundermeyer +6 more
TL;DR: In this article, the synthesis of s-block metal complexes with a double-bond has been reported, but no s block metal complexes have been identified with the double bond.
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A Mo/ller–Plesset study of the electron affinities of the diatomic hydrides XH (X=Li, B, Be, C, N, O)
Gernot Frenking,Wolfram Koch +1 more
TL;DR: In this paper, electron affinities for LiH, BeH, BH, CH, NH, and OH are computed at the MP2, MP3, and full MP4(SDTQ) order of perturbation theory employing the basis sets 6.31G(d,p), 6.311G(c,c), 6•311++G(dec), and 6. 311++G (3df,3pd), using geometries optimized at MP2/6.31C(c).
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Carbodicarbene Bismaalkene Cations: Unravelling the Complexities of Carbene versus Carbone in Heavy Pnictogen Chemistry.
Jacob E. Walley,Levi S. Warring,Guo-Cang Wang,Diane A. Dickie,Sudip Pan,Gernot Frenking,Robert J. Gilliard +6 more
TL;DR: The CDC ligand has a remarkable influence on the overall stability of the resulting low‐coordinate Bi complexes, suggesting that CDC is a superior ligand to NHC in heavy pnictogen chemistry.
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The Lewis Basicity of Diaminocarbene – A Theoretical Study of Donor–Acceptor Complexes of C(NH2)2, NH3 and CO with the Lewis Acids EF3, ECl3 (E = B, Al, Ga, In), TiF4 and TiCl4
TL;DR: In this article, the authors used large valence basis sets up to TZ+2P quality to predict the geometries and bond energies of the title compounds, showing that diaminocarbenes are much stronger bases than amines.
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The reactivity of [Zn2Cp*2 ]: trapping monovalent {*ZnZnCp*} in the metal-rich compounds [(Pd,Pt)(GaCp*)a(ZnCp*)(4-a)(ZnZnCp*)(4-a)] (a=0, 2).
Timo Bollermann,Kerstin Freitag,Christian Gemel,Rüdiger W. Seidel,Moritz von Hopffgarten,Gernot Frenking,Roland A. Fischer +6 more
TL;DR: The first results of the ongoing study on reactions of [Zn2Cp*2] with [LaTMb(GaCp)*c are presented, which found the fragment {ZnZnCp*,} with the intact covalent Zn Zn linkage being trapped as a one-electron ligand in the coordination sphere of a transition metal.
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