Frank W. Heinemann
University of Erlangen-Nuremberg
454 Papers
4.5K Citations
Frank W. Heinemann is an academic researcher from University of Erlangen-Nuremberg. The author has contributed to research in topics: Ligand & Chemistry. The author has an hindex of 50, co-authored 438 publications. Previous affiliations of Frank W. Heinemann include University of California, San Diego & University of Freiburg.
Chat about Author
Papers
Synthesis, structure and reactivity of complexes containing [M(S2)2] fragments (M=Ru, Os; (S2)2−=1,2-benzenedithiolate (2−)) ☆
TL;DR: In this article, the solid state structures of 1, 2 and 3 were determined by X-ray crystal structure analysis and a comparison of relevant bond distance data suggests that 1,2-benzenedithiolate acts as an innocent ligand.
A New Trigonal-Bipyramidal [CuII(pytBuN3)Cl2] Complex: Synthesis, Structure and Ligand Substitution Behaviour
TL;DR: In this article, the synthesis, structure and ligand substitution mechanism of a new five-coordinate copper(II) complex with a sterically constrained pytBuN3 chelate ligand [pytN3 = 2,6-bis(3,5-di-tert-butylphenyliminomethyl)pyridine] are reported.
Studies on the Reaction of Iron(II) with NO in a Noncoordinating Ionic Liquid.
Svetlana Begel,Ralph Puchta,Jörg Sutter,Frank W. Heinemann,Lutz Dahlenburg,Rudi van Eldik,Rudi van Eldik +6 more
TL;DR: A detailed analysis of the spectra revealed that the {Fe-NO}(7) species has Fe(II)-NO(•) character in contrast to Fe(III)- NO(-) as found for the other solvents, which suggests a high local symmetry around the iron center.
Two New Imidazole-Based Heteroscorpionate Ligands
TL;DR: In this paper, the synthesis of two imidazole-based N,N,O and N, N,S ligands, 2,2-bis(N-methylimidazol-2-yl)ethanol (Hbmie) and lithium bis(nethylimide-2yl)dithioacetate Li[bmidta), are described.
Copper–Nitrene Complexes in Catalytic C ? H Amination
Yosra M. Badiei,Adriana Dinescu,Xuliang Dai,Robert M. Palomino,Frank W. Heinemann,Thomas R. Cundari,Timothy H. Warren +6 more
TL;DR: Several catalytic protocols based on Rh, Ru, Ag, Au, Cu, and other metals for the amination of benzylic or allylic C H bonds with iminoiodanes bearing electrondeficient N substituents represent useful methodologies for the transformation of C H into C N bonds.