Frank W. Heinemann
University of Erlangen-Nuremberg
454 Papers
4.5K Citations
Frank W. Heinemann is an academic researcher from University of Erlangen-Nuremberg. The author has contributed to research in topics: Ligand & Chemistry. The author has an hindex of 50, co-authored 438 publications. Previous affiliations of Frank W. Heinemann include University of California, San Diego & University of Freiburg.
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Papers
Transition metal complexes with sulfur ligands part CXXIX. Retention and reactivity of the [FeNHNHFe] chromophore in the iron sulfur diazene complex [μ-N2H2{Fe(PPr3)(‘S4’)}2] in exchange and oxidation processes. (‘S4’2− = 1,2-bis (2-mercaptophenylthio)ethane(2−))
TL;DR: In this paper, the authors proposed a base-catalyzed mechanism that involves the reversible formation of the [μ-N2H{Fe(PPr3)(‘S4’)− anion.
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Transition Metal Complexes with Sulphur Ligands, Part 151 [1]. Ligand Enforced Configurations and Low-Spin States of [FeNS4] Cores in [FeII(L)('pyS4')] Complexes with σ and σ-π Ligands (L = N2H4, pyridine, PMe3, PnPr3; 'pyS4'2- = 2,6-bis(2-mercaptophenylthiomethyl)pyridine (2-))
TL;DR: In this article, the properties of [Fe(L)('pyS₄')] complexes strongly contrast with those of Fe(L)(N))(NHS) complexes and indicate that the rigid py(CH₂)µ entity of the 'pyS³µµ µ ligand is able to enforce trans configurations and low-spin states of complexes with [FeNS⁄ ] cores.
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A Specific Route to Enantiomerically Pure Asymmetric (η6-Arene)(η4-1,5-cyclooctadiene)Ru(0) Complexes
TL;DR: In this paper, substituted (arene)-(COD)Ru species were used as starting materials for the bromine-lithium exchange reaction with nBuLi at low temperatures and the lithiated species react readily with alkyl chloroformates as electrophiles.
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Werner-Type Complexes of Uranium(III) and (IV).
Judith Riedhammer,J. Rolando Aguilar-Calderón,J. Rolando Aguilar-Calderón,Matthias E. Miehlich,Dominik P. Halter,Dominik Munz,Frank W. Heinemann,Skye Fortier,Karsten Meyer,Daniel J. Mindiola,Daniel J. Mindiola +10 more
TL;DR: Electrochemical studies of 1 revealed this species to possess two anodic waves for the U(III/IV) and U(IV/V) redox couples, with the former being chemically accessible.
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Synthesis and characterization of uranium(iv) tetrachloro complexes in bis-pyrazolylpyridine ligand environments.
TL;DR: In the solid state, complexes 2a-2d possess a distorted pentagonal-bipyramidal coordination sphere at the UIV centers and an out-of-plane shift (doop) of up to 1.12 Å, which can be explained by an increased steric pressure on the metal ions at the binding sites of the chelating ligands 1c and 1d.
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