Frank W. Heinemann
University of Erlangen-Nuremberg
454 Papers
4.5K Citations
Frank W. Heinemann is an academic researcher from University of Erlangen-Nuremberg. The author has contributed to research in topics: Ligand & Chemistry. The author has an hindex of 50, co-authored 438 publications. Previous affiliations of Frank W. Heinemann include University of California, San Diego & University of Freiburg.
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Papers
Inert and Labile [Ru(L)(‘pyS4’)] Complexes with Rigid [RuNS4] Cores and trans‐Thiolate Donors [L = PPh3, PEt3, DMSO, CO, NO+, N2H4; ‘pyS4’2– = 2,6‐Bis(2‐mercaptophenylthio)dimethylpyridine(2–)]
TL;DR: In a quest for ruthenium complexes having [RuNS4] cores, a non-fluxional configuration, trans-thiolate donors, and exchangeable coligands L, [Ru(L)(‘pyS4’)] complexes have been synthesized as discussed by the authors.
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Synthesis and Catalytic Applications of Chiral Hydridoiridium(III) Complexes with Diamine/Bis(monophosphane) and Diamine/Diphosphane Coordination
TL;DR: The P 2 /N 2 -coordinated cis-dihydridioxyridium(III) chelate complexes were obtained by treating the respective diamine ligands with labile precursors such as [IrH2(H2NnNH2)(PR3) 2 ]BF 4 as discussed by the authors.
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Dispersion Forces Drive the Formation of Uranium–Alkane Adducts
Julie Jung,Julie Jung,Sascha T. Löffler,Jan Langmann,Frank W. Heinemann,Eckhard Bill,Giovanni Bistoni,Wolfgang Scherer,Mihail Atanasov,Mihail Atanasov,Karsten Meyer,Frank Neese +11 more
TL;DR: Findings indicate that the axial alkane molecule is held in place by guest-host effect rather than direct metal-alkane ionic or covalent interactions.
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Copper(II)- and Proton-Assisted Condensation Reactions of a Tetrapodal Pentaamine with Acetone: Formation of “Podand-cum-Macrocycle” Copper Complexes and a Protonated Bis(aminal)
TL;DR: The tetrapodal pentaamine 2,6-C5H3N[CMe(CH2NH2)2]2 (pyN4, 1) forms mononuclear complexes with CuII as discussed by the authors.
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Aryl, methyl-diplatinum complexes each with a metal–metal donor–acceptor bond and bridging 2-diphenylphosphinopyridine (PN) ligands: general synthetic approach and mechanism of isomerization
TL;DR: A mechanism for the conversion of the kinetic HH stereoisomer to the thermodynamic HT stereoisomers is suggested which involves association of X- with the N( 2)PtR'(2) center following by one-arm dissociation of one of the PN bridging ligands from the nitrogen terminal in the HH isomer, and subsequent exchange of the ligating atom and reformation of the HT arrangement.
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