This review highlights various aspects of current palladium membrane research and serves as a comprehensive bibliography covering palladium membrane preparation methods and applications. There are many promising uses for palladium membranes, although widespread use of the available technologies is constrained primarily by the high cost of palladium, lack of durability due to hydrogen embrittlement, and susceptibility to fouling. Various researchers in the field are tackling these problems and fabricating thinner palladium alloy composite membranes that better withstand contaminantion and thermal cycling. What has been accomplished to address these issues and the directions presently being explored are discussed.

Innovations in palladium membrane research

Synthesis and hydrogen permeation properties of ultrathin palladium-silver alloy membranes

Fabrication of a Thin Palladium Membrane Supported in a Porous Ceramic Substrate by Chemical-Vapor-Deposition

Coupling of steam and dry reforming of methane in catalytic fluidized bed membrane reactors

In this work, the hydrogen and deuterium transport parameters such as permeability, diffusivity, and solubility in a Pd-25 pct Ag alloy are studied, using a permeation gas phase technique and, additionally, a computer-controlled microbalance system. In the region in which Sieverts' law is valid, the hydrogen solubilities found using both techniques are in very good agreement. From permeation measurements, the surface constants for the adsorption (σk
 1) and release (σk
 2) of hydrogen and deuterium in Pd-25 pct Ag alloy are also determined. The measurements cover the temperature range from 323 to 773 K and a pressure range from 1 to 105 Pa.

Hydrogen and deuterium in Pd-25 pct Ag alloy: Permeation, diffusion, solubilization, and surface reaction

Permeation of hydrogen and deuterium through palladium-silver alloys

A Model for Predicting the Permeation of Hydrogen-Deuterium-Inert Gas Mixtures through Palladium Tubes

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Permeation of hydrogen and deuterium through palladium-silver alloys

A Model for Predicting the Permeation of Hydrogen-Deuterium-Inert Gas Mixtures through Palladium Tubes