Florian Heims
Humboldt University of Berlin
11 Papers
71 Citations
Florian Heims is an academic researcher from Humboldt University of Berlin. The author has contributed to research in topics: Ligand & Reactivity (chemistry). The author has an hindex of 8, co-authored 11 publications. Previous affiliations of Florian Heims include Humboldt State University.
Chat about Author
Papers
O-O bond formation mediated by a hexanuclear iron complex supported on a stannoxane core.
Subrata Kundu,Eduard Matito,Stephan Walleck,Florian Felix Pfaff,Florian Heims,Battist Rábay,Josep M. Luis,Beatrice Braun,Thorsten Glaser,Kallol Ray +9 more
TL;DR: It is shown that the Fe-metalated hexa non-heme assembly, 2, in the presence of 2-(tert-butylsulfonyl)-iodosylbenzene (PhIO), performs a rare O O bond formation reaction, thereby generating a Fe-(O2 · ) Fe superoxo unit.
Redox non-innocence of a N-heterocyclic nitrenium cation bound to a nickel-cyclam core.
Florian Heims,Florian Felix Pfaff,Sarah-Luise Abram,Erik R. Farquhar,Maurizio Bruschi,Claudio Greco,Kallol Ray +6 more
TL;DR: The binding of the triazolium ion to Ni enables new chemistry (formate oxidation) that is not observed in a derivative that lacks this functional group, thus the N-heterocyclic nitrenium ligand is a potentially useful and versatile reagent in transition-metal-based catalysis.
Synthesis and Spectroscopic Characterisation of a Heterodinuclear Iron(III)-Copper(II) Complex Based on an Asymmetric Dinucleating Ligand System
Florian Heims,Valeriu Mereacre,Antonella Ciancetta,Stefan Mebs,Annie K. Powell,Claudio Greco,Kallol Ray +6 more
TL;DR: The site-directed generation of a heterodinuclear FeIIICuII complex by using a new asymmetric dinucleating ligand FloH is reported in this paper.
10