Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural features and reaction patterns have emerged, and more importantly, these compounds now feature prominently in both metal-catalyzed and metal-free methodologies for the formation of B–C bonds and other processes.

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

The present Review addresses current developments related to polymer-derived ceramic nanocomposites (PDC-NCs). Different classes of preceramic polymers are briefly introduced and their conversion into ceramic materials with adjustable phase compositions and microstructures is presented. Emphasis is set on discussing the intimate relationship between the chemistry and structural architecture of the precursor and the structural features and properties of the resulting ceramic nanocomposites. Various structural and functional properties of silicon-containing ceramic nanocomposites as well as different preparative strategies to achieve nano-scaled PDC-NC-based ordered structures are highlighted, based on selected ceramic nanocomposite systems. Furthermore, prospective applications of the PDC-NCs such as high-temperature stable materials for thermal protection systems, membranes for hot gas separation purposes, materials for heterogeneous catalysis, nano-confinement materials for hydrogen storage applications as well as anode materials for secondary ion batteries are introduced and discussed in detail.

https://www.mdpi.com/2079-4991/5/2/468/pdf

Ceramic Nanocomposites from Tailor-Made Preceramic Polymers

DFT Studies on the Mechanisms of the Platinum-Catalyzed Diboration of Acyclic α,β-Unsaturated Carbonyl Compounds

The diboration of alkynes has become the most straightforward and powerful method for the synthesis of functionalized 1,2-diborylalkenes, which are widely used as building blocks in organic synthesis. The present review provides a comprehensive summary of the diboration of alkynes, including platinum-, palladium-, cobalt-, copper-, iridium-, gold-, iron-, base- and small organic molecule-catalyzed diboration, direct and metal-free diboration, and base-promoted diboration of alkynes up to early 2017. The reaction conditions, regio- and stereoselectivities, and mechanisms are summarized in detail. Moreover, synthetic applications and perspectives on the diboration of alkynes are also discussed.

Catalytic and catalyst-free diboration of alkynes

Radical addition to isonitriles (isocyanides) starts and continues all the way to the transition state (TS) mostly as a simple addition to a polarized π-bond. Only after the TS has been passed, the spin density moves to the α-carbon to form the imidoyl radical, the hallmark intermediate of the 1,1-addition-mediated cascades. Addition of alkyl, aryl, heteroatom-substituted, and heteroatom-centered radicals reveals a number of electronic, supramolecular, and conformational effects potentially useful for the practical control of isonitrile-mediated radical cascade transformations. Addition of alkyl radicals reveals two stereoelectronic preferences. First, the radical attack aligns the incipient C···C bond with the aromatic π-system. Second, one of the C–H/C–C bonds at the radical carbon eclipses the isonitrile N–C bond. Combination of these stereoelectronic preferences with entropic penalty explains why the least exergonic reaction (addition of the t-Bu radical) is also the fastest. Heteroatomic radicals rev...

Isonitriles as Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy in Radical Additions.

1,1-Diboration of Isocyanides with [2]Borametalloarenophanes

Diboration of Dialkynes with [2]Boraferrocenophanes

Unexpected Generation of Diastereomers by Double Diboration of a Dialkyne

The subject of this paper is Beurling’s celebrated extension of the Riemann mapping theorem [5]. Our point of departure is the observation that the only known proof of the Beurling-Riemann mapping theorem (due to Beurling) contains a number of gaps which seem inherent in Beurling’s geometric and approximative approach. We provide a complete proof of the Beurling-Riemann mapping theorem by combining Beurling’s geometric method with a number of new analytic tools, notably Hp-space techniques and methods from the theory of Riemann-Hilbert-Poincare problems. One additional advantage of this approach is that it leads to an extension of the Beurling-Riemann mapping theorem for analytic maps with prescribed branching. Moreover, it allows a complete description of the boundary regularity of solutions in the (generalized) Beurling-Riemann mapping theorem extending earlier results that have been obtained by PDE techniques. We finally consider the question of uniqueness in the extended Beurling-Riemann mapping theorem.

Beurling’s free boundary value problem in conformal geometry

The subject of this paper is Beurling's celebrated extension of the Riemann mapping theorem \cite{Beu53}. Our point of departure is the observation that the only known proof of the Beurling-Riemann mapping theorem contains a number of gaps which seem inherent in Beurling's geometric and approximative approach. We provide a complete proof of the Beurling-Riemann mapping theorem by combining Beurling's geometric method with a number of new analytic tools, notably $H^p$-space techniques and methods from the theory of Riemann-Hilbert-Poincare problems. One additional advantage of this approach is that it leads to an extension of the Beurling-Riemann mapping theorem for analytic maps with prescribed branching. Moreover, it allows a complete description of the boundary regularity of solutions in the (generalized) Beurling-Riemann mapping theorem extending earlier results that have been obtained by PDE techniques. We finally consider the question of uniqueness in the extended Beurling-Riemann mapping theorem.

Beurling's free boundary value problem in conformal geometry

Handle everyday research tasks with reliable, citation-backed results

Your personal Research Agent to handle research tasks with citation-backed results

Popular Tasks used by Researchers

How can I help with your research?

Meet SciSpace

Get more enhanced response by uploading the PDFs you want me to reference.

No relevant PDFs in your library

SciSpace is the AI research assistant for academics. Run systematic literature reviews on 280M+ papers, and write papers with cited sources. Trusted by 1M+ students, PhDs & researchers.

SciSpace | AI for Research

Analyze PDFs

Code & Manuscripts

Funding & Grants

Literature & Patents

Medical & Clinical Data

Systematic Review

Visualize & Present

Web & Data

Build a Google Scholar-like website for your research.

Build a website

Create charts and images for your research

Create a Chart

Write a paper for submission to a journal

Draft a manuscript

Patent Search

Design eye-catching scientific posters in minutes.

Scientific Poster Generation

Systematic Literature Review

One task is running at the moment. Your messages will be shown right after.

Drag and drop or click here to browse

Loved by <highlight>1 million+</highlight> researchers

Extract a list of specific topics and their sources from unstructured text

Topics

Compare and analyze relevant papers that matches with your search

Papers

Get insights from PDFs and bookmarked papers from your library

My library

Recent searches

Try searching for:

Catch AI-generated content in scholarly and non-scholarly content

{ai} Detector

Ai Writer

Get PDF Summaries, highlighted text explanations 

Chat with PDF

Effortlessly create in-text citations and bibliographies in APA and 2,500 other formats

Citation generator

Get explanations, summaries, and answers on academic papers

Ease up your research workflow with {scispace}'s cohort of exciting AI tools

Elevate your academic writing skills and convey your ideas the way you want

Paraphraser

Explore our range of reading and writing tools

Your file is being prepared and should be ready in a few minutes. If it's a large file, it might take a bit longer. You can close this window, and we'll email you the file when it's done.

You have reached a maximum limit of <strong>{limit}</strong> columns in the table. Remove at least <strong>1</strong> column to add or create another one.

Florian Bauer

Author Tools

Chat about Author